Ma Jingdong, Yu Guoyan, Wang Xianmin, Li Jun, Wu Jingquan, Wang Xianzhang
School of Mechanical Engineering, Guangdong Ocean University, Zhanjiang 524088, China.
Guangdong Provincial Marine Equipment and Manufacturing Engineering Technology Research Center, Zhanjiang 524088, China.
Polymers (Basel). 2022 Oct 3;14(19):4137. doi: 10.3390/polym14194137.
Polymeric matrix composites have been widely used in the marine field. In this study, the tribological behavior under seawater-lubricated conditions of pure Polyamide 12 (PA12), micron-SiC and nanometer SiC and SiO particle-reinforced PA12 composites, which are prepared by selective laser sintering (SLS), were studied. The seawater absorption, hardness, contact angle and tribology performance were investigated. The results show that the addition of micron- and nano-SiC particles and nano-SiO particles could decrease the seawater adsorption and contact angle, and increase the hardness. Under seawater conditions, the addition of micro SiC particles can reduce the friction coefficient and wear loss, whereas the addition of nano-SiC and -SiO particles increases the corresponding values. The specimen printed with recycled powder has a higher friction coefficient, while having a better wear resistance. However, it increases the width and depth of the wear track in some locations. The wear mechanisms of the composite specimens are also analyzed. This was the result of the combined effects of fatigue wear and abrasive wear under seawater conditions. The latter plays a dominant role under seawater conditions. This study may provide a valuable reference for the further research and application of polymeric matrix composites in marine engineering equipment.
聚合物基复合材料已在海洋领域得到广泛应用。在本研究中,对通过选择性激光烧结(SLS)制备的纯聚酰胺12(PA12)、微米碳化硅和纳米碳化硅及二氧化硅颗粒增强的PA12复合材料在海水润滑条件下的摩擦学行为进行了研究。研究了其海水吸收率、硬度、接触角和摩擦学性能。结果表明,添加微米和纳米碳化硅颗粒以及纳米二氧化硅颗粒可降低海水吸附和接触角,并提高硬度。在海水条件下,添加微米碳化硅颗粒可降低摩擦系数和磨损损失,而添加纳米碳化硅和二氧化硅颗粒则会提高相应数值。用回收粉末打印的试样具有较高的摩擦系数,同时具有较好的耐磨性。然而,它在某些位置增加了磨损轨迹的宽度和深度。还分析了复合试样的磨损机制。这是海水条件下疲劳磨损和磨粒磨损共同作用的结果。在海水条件下,后者起主导作用。本研究可为聚合物基复合材料在海洋工程装备中的进一步研究和应用提供有价值的参考。