Graduate Institute of Environmental Engineering, National Central University, Chung-Li, Taoyuan County, 320, Taiwan.
Environ Sci Pollut Res Int. 2013 Aug;20(8):5654-64. doi: 10.1007/s11356-013-1575-3. Epub 2013 Mar 1.
The development of a complete set of extensive studies combining both the preparation factors of catalysts and photocatalytic experimental factors for the photodegradation of methylene blue, crystal violet, and Congo red using effective nano zinc oxide (ZnO) obtained from polysaccharides (chitosans, corn starch, and sodium alginate) as chelating agents was the main objective of this study. The influence of nature of polysaccharides, ratio of reactants, calcination temperatures during preparation process, and effects of photocatalytic experimental conditions on photodegradation was investigated. Corn starch and sodium alginate were found to be effective chelating agents and optimum preparation parameters were set as 3:3 % ratio of reactants and 450 °C calcination temperature to prepare nano ZnO with good photocatalytic activity. The order of organic dyes based on their photodegradation rates was arranged as crystal violet > methylene blue > Congo red. Our findings shed light on the optimization of both preparation conditions of photocatalysts and photocatalytic experimental conditions.
本研究的主要目标是开发一整套广泛的研究,结合催化剂的制备因素和光催化实验因素,使用从多糖(壳聚糖、玉米淀粉和海藻酸钠)作为螯合剂获得的有效纳米氧化锌(ZnO)来光降解亚甲基蓝、结晶紫和刚果红。研究了多糖的性质、反应物比例、制备过程中的煅烧温度以及光催化实验条件对光降解的影响。发现玉米淀粉和海藻酸钠是有效的螯合剂,最佳制备参数为反应物比例为 3:3%和 450°C 的煅烧温度,以制备具有良好光催化活性的纳米 ZnO。根据光降解速率对有机染料进行了排序,结果为结晶紫>亚甲基蓝>刚果红。我们的研究结果为优化催化剂的制备条件和光催化实验条件提供了依据。