Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India.
Inorg Chem. 2013 Mar 18;52(6):2927-32. doi: 10.1021/ic302611a. Epub 2013 Mar 4.
Metal-catalyzed halogenation of the C-H bond and decarbonylation of aldehyde are conventionally done in nature. However, metal-mediated decarbonylative halogenation is unknown. We have developed the first metal-mediated decarbonylative halogenation reaction starting from the divanadium oxoperoxo complex K3V(5+)2(O2(2-))4(O(2-))2(μ-OH) (1). A concerted decarbonylative halogenation reaction was proposed based on experimental observations.
金属催化的 C-H 键卤化和醛的脱羰反应在自然界中很常见。然而，金属介导的脱羰卤化反应尚不清楚。我们开发了首例从钒氧过氧配合物 K3V(5+)2(O2(2-))4(O(2-))2(μ-OH) (1)出发的金属介导的脱羰卤化反应。根据实验观察，提出了协同脱羰卤化反应的假设。
