Department of Viticulture & Enology, University of California, Davis, Davis, California 95616, United States.
J Agric Food Chem. 2013 Apr 3;61(13):3320-34. doi: 10.1021/jf3051736. Epub 2013 Mar 21.
A Californian Cabernet Sauvignon was stored for 6 months at three different constant temperatures to study the combined effects of storage temperature and packaging configuration. Glass bottles with natural cork, synthetic cork, and screw cap closure, as well as two Bag-in-Box treatments, were used in the experiment. A trained sensory panel was able to detect significant changes in aroma, flavor, taste, mouthfeel, and color attributes among the samples, differences that were found also with various chemical and physical measurements (volatile profile, polyphenol pattern, enological parameters, color space). Additionally, two commonly used polyphenol assays were compared to each other in terms of their ability to detect the changes in the polyphenol profile. Generally, sample changes were more pronounced due to the different storage temperatures, with 30 sensory attributes differing significantly among the three different storage temperatures, while only 17 sensory attributes showed a significant packaging effect. With increasing storage temperature the packaging effect became more pronounced, resulting in the largest changes in the Bag-in-Box samples stored at the highest temperature of 40 °C. At the highest storage temperature, all wines showed oxidized characters, independent of the wine packaging configurations, but to a varying degree. Generally, wines that received highest oxygen amounts and storage temperatures were much lighter, less red, and more brown-yellow at the end of the 6-month storage period, compared to their counterparts stored at 10 °C. These changes in color and polyphenols, respectively, were also detected with the two spectrophotometric assays. With increasing storage temperature both assays measured reduced concentrations in total phenols and total anthocyanins, while total tannins, degree of ionized anthocyanins, and color density increased. Various volatile compounds differed significantly among the samples, with largest relative concentration changes in acetates, organic acids, and alcohols, in good agreement with previous literature reports, with some being well correlated to specific sensory attributes too; for example, various acetates correlated to cherry and fruit aromas and flavors. The study shows that storage at elevated temperatures could be a valuable tool for wine packaging screening and testing new and improved wine packaging types under the worst conditions, which are unfortunately not unrealistic.
一种加利福尼亚赤霞珠葡萄酒在三种不同的恒定温度下储存了 6 个月,以研究储存温度和包装配置的综合影响。实验中使用了带有天然软木塞、合成软木塞和螺旋盖的玻璃瓶,以及两种盒中袋处理方式。一个经过训练的感官小组能够检测到样品在香气、风味、口感、口感和颜色属性方面的显著变化,通过各种化学和物理测量(挥发性成分、多酚模式、酿造参数、颜色空间)也发现了这些差异。此外,还比较了两种常用的多酚测定方法在检测多酚谱变化方面的能力。一般来说,由于不同的储存温度,样品的变化更为明显,三种不同储存温度下有 30 个感官属性差异显著,而只有 17 个感官属性显示出显著的包装效果。随着储存温度的升高,包装效果变得更加明显,导致在最高温度为 40°C 的盒中袋样品中发生了最大的变化。在最高储存温度下,所有葡萄酒都表现出氧化特征,与葡萄酒包装配置无关,但程度不同。一般来说,在 6 个月储存期结束时,与在 10°C 下储存的葡萄酒相比,接收最高氧气量和储存温度的葡萄酒颜色更浅、更红、更黄棕色。这两种分光光度测定法也检测到了颜色和多酚的这些变化。随着储存温度的升高,两种测定方法都测量到总酚和总花青素浓度降低,而游离态花青素、单宁总含量和颜色密度增加。样品中各种挥发性化合物差异显著,其中乙酸酯、有机酸和醇的相对浓度变化最大,与之前的文献报道一致,其中一些与特定的感官属性也有很好的相关性;例如,各种乙酸酯与樱桃和水果香气和风味相关。该研究表明,在高温下储存可以成为葡萄酒包装筛选的有效工具,并在最坏的条件下测试新的和改进的葡萄酒包装类型,不幸的是,这些条件并不现实。