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链状聚[[[二水合铜（II）]-双-[μ-1,5-双-（1H-咪唑-1-基）戊烷-κ(2) N (3):N (3')]]萘-1,5-二磺酸盐]

catena-Poly[[[diaqua-copper(II)]-bis-[μ-1,5-bis-(1H-imidazol-1-yl)pentane-κ(2) N (3):N (3')]] naphthalene-1,5-disulfonate].

作者信息

Zhang Lai-Ping, Wen Shu-Tang, Fu Xiao-Ning

机构信息

Department of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang 453000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Dec 1;68(Pt 12):m1505. doi: 10.1107/S1600536812045679. Epub 2012 Nov 17.

DOI:10.1107/S1600536812045679
PMID:23468720
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3588755/
Abstract

In the title complex, {Cu(C11H16N4)2(H2O)2} n , the Cu(II) atom, lying on an inversion center, is six-coordinated by two water mol-ecules and four N atoms from four 1,5-bis-(1H-imidazol-1-yl)pentane (biim-5) ligands in a distorted octa-hedral geometry. Adjacent Cu(II) atoms are linked by two biim-5 ligands, forming a chain along [111]. Two atoms of the pentane group are disordered over two sets of sites, with an occupancy ratio of 0.554 (18):0.446 (18). Inter-molecular O-H⋯O hydrogen bonds link the chains and the centrosymmetric naphthalene-1,5-disulfonate anions into a layer structure parallel to (0-11).

摘要

在标题配合物{Cu(C₁₁H₁₆N₄)₂(H₂O)₂}ₙ中，位于对称中心的Cu(II)原子由两个水分子和来自四个1,5-双(1H-咪唑-1-基)戊烷（biim-5）配体的四个N原子以扭曲的八面体几何构型进行六配位。相邻的Cu(II)原子通过两个biim-5配体相连，沿[111]方向形成一条链。戊烷基的两个原子在两组位置上无序分布，占有率为0.554 (18):0.446 (18)。分子间的O-H⋯O氢键将这些链和中心对称的萘-1,5-二磺酸盐阴离子连接成平行于(0-11)的层状结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e3f/3588755/300badd8573a/e-68-m1505-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e3f/3588755/300badd8573a/e-68-m1505-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e3f/3588755/300badd8573a/e-68-m1505-fig1.jpg

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本文引用的文献

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2
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3
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Angew Chem Int Ed Engl. 2004 Dec 17;44(1):72-5. doi: 10.1002/anie.200461214.