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链状聚[[三（乙腈-κN）镨（III）]三（μ-三氟甲磺酸根-κ（2）O:O′）]

catena-Poly[[tris-(acetonitrile-κN)praseodymium(III)]tris-(μ-trifluoro-methane-sulfonato-κ(2) O:O')].

作者信息

Apostolidis Christos, Walter Olaf

机构信息

European Commission, Joint Research Centre, Institute for Transuranium Elements, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m21. doi: 10.1107/S1600536812049525. Epub 2012 Dec 8.

DOI:10.1107/S1600536812049525
PMID:23476322
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3588273/
Abstract

In the colourless title compound, [Pr(CF3O3S)3(CH3CN)3] n , the three trifluoro-methane-sulfonate anions form three bridges via O:O'-coordination between two Pr(III) atoms. The structure contains [Pr(NCMe)3-μ2(OTf)3-Pr(NCMe)3-μ2(OTf)3] n (NCMe is acetonitrile; OTf is trifluoromethanesulfonate) chains parallel to the a axis. The Pr(III) atom is nine-coordinate in a distorted tricapped trigonal-prismatic environment.

摘要

在无色标题化合物[Pr(CF₃O₃S)₃(CH₃CN)₃]ₙ中，三个三氟甲磺酸根阴离子通过两个Pr(III)原子之间的O:O'配位形成三个桥。该结构包含平行于a轴的[Pr(NCMe)₃-μ₂(OTf)₃-Pr(NCMe)₃-μ₂(OTf)₃]ₙ链（NCMe为乙腈；OTf为三氟甲磺酸根）。Pr(III)原子在扭曲的三帽三角棱柱环境中为九配位。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2de/3588273/2c0d4118454f/e-69-00m21-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2de/3588273/2c0d4118454f/e-69-00m21-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d2de/3588273/2c0d4118454f/e-69-00m21-fig1.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Practical synthetic routes to solvates of U(OTf)3: X-ray crystal structure of [U(OTf)3(MeCN)3]n, a unique U(III) coordination polymer.合成三氟甲磺酸铀（U(OTf)3）溶剂化物的实用路线：[U(OTf)3(MeCN)3]n的X射线晶体结构，一种独特的U(III)配位聚合物。
Inorg Chem. 2005 Aug 22;44(17):6115-21. doi: 10.1021/ic0505652.