• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

二氯化双（4,4'-硫烷二基二吡啶鎓）四氯合镍（II）

Bis(4,4'-sulfanediyldipyridinium) tetra-chloridonickelate(II) dichloride.

作者信息

Werner Julia, Jess Inke, Näther Christian

机构信息

Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m59. doi: 10.1107/S1600536812050623. Epub 2012 Dec 15.

DOI:10.1107/S1600536812050623
PMID:23476352
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3588299/
Abstract

In the title compound, (C10H10N2S)2[NiCl4]Cl2, the Ni(2+) cation is tetra-hedrally coordinated by four chloride anions. Two 4,4'-sulfanediyldipyridinium cations and two non-coordinating chloride anions are connected via N-H⋯Cl hydrogen-bonding inter-actions into 20-membered rings, in the middle of which are situated the NiCl4 complex anions. These rings are stacked in the b-axis direction. The Ni(2+) cation is located on a twofold rotation axis, whereas the chloride anions and the 4,4'-sulfanediyldipyridinium cations occupy general positions.

摘要

在标题化合物（C₁₀H₁₀N₂S）₂[NiCl₄]Cl₂中，Ni²⁺阳离子由四个氯离子以四面体方式配位。两个4,4'-硫烷二基二吡啶鎓阳离子和两个非配位氯离子通过N-H⋯Cl氢键相互作用连接成20元环，[NiCl₄]²⁻络合阴离子位于这些环的中间。这些环沿b轴方向堆积。Ni²⁺阳离子位于二重旋转轴上，而氯离子和4,4'-硫烷二基二吡啶鎓阳离子占据一般位置。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ba49/3588299/4b99c2da698e/e-69-00m59-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ba49/3588299/87c939324695/e-69-00m59-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ba49/3588299/4b99c2da698e/e-69-00m59-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ba49/3588299/87c939324695/e-69-00m59-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ba49/3588299/4b99c2da698e/e-69-00m59-fig2.jpg

相似文献

1
Bis(4,4'-sulfanediyldipyridinium) tetra-chloridonickelate(II) dichloride.二氯化双（4,4'-硫烷二基二吡啶鎓）四氯合镍（II）
Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m59. doi: 10.1107/S1600536812050623. Epub 2012 Dec 15.
2
Crystal structure, thermal and fluorescence properties of 2,2':6',2''-terpyridine-1,1',1''-triium tetra-chlorido-nickelate(II) chloride.二氯化四氯合镍（II）-2,2':6',2''-三联吡啶-1,1',1''-三铵盐的晶体结构、热性质和荧光性质
Acta Crystallogr E Crystallogr Commun. 2017 Nov 28;73(Pt 12):1937-1941. doi: 10.1107/S2056989017016784. eCollection 2017 Dec 1.
3
Unexpected formation and crystal structure of tetra-kis-(1H-pyrazole-κN (2))-palladium(II) dichloride.二氯四-（1H-吡唑-κN(2)）-钯（II）的意外形成及晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Nov 15;70(Pt 12):486-8. doi: 10.1107/S160053681402460X. eCollection 2014 Dec 1.
4
Bis[μ-1,3-bis-(di-phenyl-phosphan-yl)propane-κ(2) P:P']digold(I) tetra-chloridonickelate(II) diethyl ether monosolvate.双[μ-1,3-双（二苯基膦基）丙烷-κ(2)P:P']二金（I）四氯合镍（II）二乙醚单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2013 May 22;69(Pt 6):m339. doi: 10.1107/S1600536813013470. Print 2013 Jun 1.
5
Crystal structure of di-chlorido-bis-(4-ethyl-aniline-κN)zinc.二氯双（4-乙基苯胺-κN）锌的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jan 14;71(Pt 2):m21-2. doi: 10.1107/S2056989014027832. eCollection 2015 Feb 1.
6
Tetra-amminepalladium(II) dichloride ammonia tetra-solvate.二氯四氨合钯（II）四氨溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2014 Jun 7;70(Pt 7):i32. doi: 10.1107/S1600536814012355. eCollection 2014 Jul 1.
7
4-Hydr-oxy-2,2,6,6-tetra-methyl-piperidinium chloride-hydroxonium chloride (3/1).4-羟基-2,2,6,6-四甲基哌啶鎓氯化物-氢氧鎓氯化物（3/1）
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 25;64(Pt 2):o512. doi: 10.1107/S1600536808002158.
8
Bis{3-[2-(methyl-sulfon-yl)pyrimidin-4-yl]pyridinium} tetra-chloridocadmium.双{3-[2-(甲基磺酰基)嘧啶-4-基]吡啶鎓}四氯化镉
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1813. doi: 10.1107/S1600536811045995. Epub 2011 Nov 23.
9
Bis(2-amino-4-methyl-pyridinium) tetra-chloridocuprate(II).二氯·双（2-氨基-4-甲基吡啶）合铜（II）
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 17;65(Pt 1):m73-4. doi: 10.1107/S1600536808041652.
10
Di-μ-chlorido-bis-[bis-(ethyl-enediamine-κN,N')cadmium(II)] dichloride.二-μ-氯-双-[双-(乙二胺-κN,N')镉(II)]二氯化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 24;66(Pt 1):m98. doi: 10.1107/S1600536809054804.

本文引用的文献

1
Coexistence of metamagnetism and slow relaxation of the magnetization in a cobalt thiocyanate 2D coordination network.
Angew Chem Int Ed Engl. 2011 Jul 18;50(30):6920-3. doi: 10.1002/anie.201007899. Epub 2011 Jun 10.
2
A rational route to SCM materials based on a 1-D cobalt selenocyanato coordination polymer.基于一维钴硒氰酸配位聚合物的 SCM 材料的合理路线。
Chem Commun (Camb). 2011 Jul 7;47(25):7104-6. doi: 10.1039/c1cc12273h. Epub 2011 May 27.
3
Solid-state transformation of [Co(NCS)2(pyridine)4] into [Co(NCS)2(pyridine)2]n: from Curie-Weiss paramagnetism to single chain magnetic behaviour.[Co(NCS)2(pyridine)4]到[Co(NCS)2(pyridine)2]n的固态相变：从居里-外斯顺磁体到单链磁体行为。
Dalton Trans. 2010 Dec 7;39(45):11019-26. doi: 10.1039/c0dt00904k. Epub 2010 Oct 14.
4
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.