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基于一维钴硒氰酸配位聚合物的 SCM 材料的合理路线。

A rational route to SCM materials based on a 1-D cobalt selenocyanato coordination polymer.

机构信息

Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Str. 2, 24118, Kiel, Germany.

出版信息

Chem Commun (Camb). 2011 Jul 7;47(25):7104-6. doi: 10.1039/c1cc12273h. Epub 2011 May 27.

DOI:10.1039/c1cc12273h
PMID:21617809
Abstract

Thermal annealing of a discrete complex with terminal SeCN anions and monodentate coligands enforces the formation of a 1D cobalt selenocyanato coordination polymer that shows slow relaxation of the magnetization. Therefore, this approach offers a rational route to 1D materials that might show single chain magnetic behaviour.

摘要

热退火离散配合物与末端 SeCN 阴离子和单齿配位体，强制形成一维钴硒氰酸根配位聚合物，表现出缓慢的磁化弛豫。因此，这种方法为可能表现出单链磁行为的一维材料提供了一种合理的途径。

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