Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr, Germany.
Chem Commun (Camb). 2013 Apr 18;49(30):3140-2. doi: 10.1039/c3cc40382c. Epub 2013 Mar 11.
Heterobimetallic complexes derived from carbodiphosphoranes or phosphinidene-carbene adducts are reported, in which the central atom accepts two lone-pairs from two different donor ligands and - at the same time - donates two lone-pairs to two different metal centers. Therefore these complexes are carbogenic yet captodative chiral entities.
报道了源自碳二膦烷或磷亚胺-碳烯加合物的杂双金属配合物，其中中心原子接受来自两个不同给体配体的两个孤对电子，同时向两个不同的金属中心提供两个孤对电子。因此，这些配合物是碳杂化的同时又是受捕获的手性实体。
