Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, Japan.
J Am Chem Soc. 2013 Mar 27;135(12):4612-5. doi: 10.1021/ja3122872. Epub 2013 Mar 18.
A Ca(2+) porous coordination polymer with 1D channels was functionalized by the postsynthesis addition of LiCl to enhance the H(+) conductivity. The compound showed over 10(-2) S cm(-1) at 25 °C and 20% relative humidity. Pulse-field gradient NMR elucidated that the fast H(+) conductivity was achieved by the support of Li(+) ion movements in the channel.
一种具有一维通道的 Ca(2+) 多孔配位聚合物通过后合成添加 LiCl 进行功能化，以提高 H(+) 电导率。该化合物在 25°C 和 20%相对湿度下表现出超过 10(-2) S cm(-1)的电导率。脉冲场梯度 NMR 表明，Li(+)离子在通道中的运动为快速 H(+) 电导率提供了支持。
