由供体和受体构筑单元组成的导电多孔配位聚合物 Cu[Cu(pdt)2]。
Electroconductive porous coordination polymer Cu[Cu(pdt)2] composed of donor and acceptor building units.
机构信息
Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8575, Japan.
出版信息
Inorg Chem. 2009 Oct 5;48(19):9048-50. doi: 10.1021/ic802117q.
PMID:19067544
Abstract
We synthesized a new porous coordination polymer Cu[Cu(pdt)2], which shows relatively high electrical conductivity (6 x 10(-4) S cm(-1) at 300 K) by the introduction of electron donors and acceptors as building units. This compound is applicable as a porous electrode with high power density. In addition, this compound forms a triangular spin lattice and shows spin frustration.
摘要
我们合成了一种新型的多孔配位聚合物 Cu[Cu(pdt)2]，通过引入电子给体和受体作为构筑单元，该化合物表现出较高的电导率（300 K 时为 6×10(-4) S cm(-1)）。该化合物可用作具有高功率密度的多孔电极。此外，该化合物形成了一个三角形的自旋晶格，并表现出了自旋阻挫。
Zotero 插件