Department of Chemistry and Beijing Key Laboratory of Energy Conversion and Storage Materials, Beijing Normal University, Beijing 100875, People's Republic of China.
Inorg Chem. 2013 Apr 1;52(7):3582-4. doi: 10.1021/ic302556r. Epub 2013 Mar 13.
In this paper, a novel three-dimensional (3D) porous lanthanide-organic framework, Eu2(μ4-pmdc)2(OH)2·3H2O (1), which is stable up to 400 °C, has been hydrothermally synthesized and characterized. It shows intriguing single-crystal-to-single-crystal transformation and reversible dehydration/rehydration phenomenon upon removal and rebinding of the lattice water molecules, which is supported by single-crystal X-ray diffraction, powder X-ray diffraction, and photoluminescence data.
在本文中，我们合成并表征了一种新型的三维（3D）多孔镧系有机框架材料 Eu2(μ4-pmdc)2(OH)2·3H2O（1），其在 400°C 以下稳定。该材料在去除和重新结合晶格水分子时表现出有趣的单晶到单晶的转变和可逆的脱水/水合现象，单晶 X 射线衍射、粉末 X 射线衍射和光致发光数据对此现象提供了支持。
