CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France.
Dalton Trans. 2013 Jul 7;42(25):9148-56. doi: 10.1039/c3dt33082f. Epub 2013 Mar 13.
Well defined star copolymers have been prepared by copper-catalyzed atom transfer radical copolymerization of styrene and styryldiphenylphosphine starting from a modified Boltorn™ H30 multifunctional initiator. These polymers and an analogue obtained by debromination of the arm ends with nBu3SnH have been used in combination with [Rh(acac)(CO)2] for the homogeneous phase hydroformylation of 1-octene.
已经通过铜催化原子转移自由基共聚反应，由改性的 Boltorn™ H30 多功能引发剂引发苯乙烯和苯乙烯二苯膦，制备了具有明确结构的星型共聚物。这些聚合物以及通过 nBu3SnH 脱溴臂端得到的类似物，已与[Rh(acac)(CO)2]一起用于 1-辛烯的均相氢甲酰化反应。
