Vanelderen Pieter, Hadt Ryan G, Smeets Pieter J, Solomon Edward I, Schoonheydt Robert A, Sels Bert F
Center for Surface Chemistry and Catalysis, K.U.Leuven, Kasteelpark Arenberg 23, B-3001 Leuven, Belgium.
J Catal. 2011 Dec 1;284(2):157-164. doi: 10.1016/j.jcat.2011.10.009. Epub 2011 Nov 14.
The present work highlights recent advances in elucidating the methane oxidation mechanism of inorganic Cu-ZSM-5 biomimic and in identifying the reactive intermediates that are involved. Such molecular understanding is important in view of upgrading abundantly available methane, but also to comprehend the working mechanism of genuine Cu-containing oxidation enzymes.
本工作突出了在阐明无机Cu-ZSM-5仿生材料的甲烷氧化机制以及确定其中涉及的反应中间体方面的最新进展。鉴于将大量可用的甲烷进行升级，这种分子层面的理解很重要，而且对于理解真正含铜氧化酶的工作机制也很重要。
