State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, China.
Chem Commun (Camb). 2013 May 11;49(38):3925-36. doi: 10.1039/c3cc00039g. Epub 2013 Mar 19.
Porous organic frameworks (POFs) as an important subclass of nanoporous materials are of great interest in materials science. In recent years, the discovery and creation of POFs with excellent properties for advanced applications have attracted much attention and intensive efforts have been contributed to this field. As a result, the design of materials with multi-functionalities is an ever-pursued dream of materials scientists and engineers. In this respect, a new concept based on topology chemistry is introduced for the rational and targeted synthesis of POF materials. The present feature article provides an overview of the relationship between building blocks or starting monomers, underlying topological nets, and pre-determined structures. Several important nets are included successively from one to three dimensions. In addition, special emphasis is given to the advanced applications of designed POF materials in the current paper.
多孔有机骨架（POFs）作为纳米多孔材料的一个重要子类，在材料科学领域具有重要的研究意义。近年来，具有优异性能的 POFs 的发现和创造，为先进应用吸引了广泛关注，人们也为此领域投入了大量的努力。因此，多功能材料的设计是材料科学家和工程师的一个追求梦想。在这方面，基于拓扑化学的新概念被引入到 POF 材料的合理和有针对性的合成中。本文综述了构筑块或起始单体、基础拓扑网络和预定结构之间的关系。本文依次从一维到三维，包含了几个重要的网络。此外，本文还特别强调了设计的 POF 材料在当前研究中的先进应用。
