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用于医疗应用的 Mg-Dy-Gd-Zr 合金的微观结构、力学性能和腐蚀性能。

Microstructure, mechanical and corrosion properties of Mg-Dy-Gd-Zr alloys for medical applications.

机构信息

Helmholtz Zentrum Geesthacht, Magnesium Innovation Centre, Institute of Materials Research, Max-Planck-Str. 1, D-21502 Geesthacht, Germany.

出版信息

Acta Biomater. 2013 Nov;9(10):8499-508. doi: 10.1016/j.actbio.2013.03.017. Epub 2013 Mar 20.

Abstract

In previous investigations, a Mg-10Dy (wt.%) alloy with a good combination of corrosion resistance and cytocompatibility showed great potential for use as a biodegradable implant material. However, the mechanical properties of Mg-10Dy alloy are not satisfactory. In order to allow the tailoring of mechanical properties required for various medical applications, four Mg-10(Dy+Gd)-0.2Zr (wt.%) alloys were investigated with respect to microstructure, mechanical and corrosion properties. With the increase in Gd content, the number of second-phase particles increased in the as-cast alloys, and the age-hardening response increased at 200°C. The yield strength increased, while the ductility reduced, especially for peak-aged alloys with the addition of Gd. Additionally, with increasing Gd content, the corrosion rate increased in the as-cast condition owing to the galvanic effect, but all the alloys had a similar corrosion rate (~0.5 mm year(-1)) in solution-treated and aged condition.

摘要

在之前的研究中,Mg-10Dy(重量百分比)合金具有良好的耐腐蚀性和细胞相容性,具有作为可生物降解植入材料的巨大潜力。然而,Mg-10Dy 合金的力学性能并不令人满意。为了使各种医疗应用所需的机械性能得到定制,研究了四种 Mg-10(Dy+Gd)-0.2Zr(重量百分比)合金的微观结构、力学性能和腐蚀性能。随着 Gd 含量的增加,铸态合金中的第二相颗粒数量增加,在 200°C 时时效硬化响应增加。屈服强度增加,而延展性降低,特别是添加 Gd 的时效峰值合金。此外,随着 Gd 含量的增加,由于电偶效应,铸态合金的腐蚀速率增加,但所有合金在固溶处理和时效状态下的腐蚀速率相似(~0.5mm/年)。

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