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镁合金腐蚀机制、防护及新型涂层材料的最新研究进展:综述

Recent research advances on corrosion mechanism and protection, and novel coating materials of magnesium alloys: a review.

作者信息

Wei Liangyu, Gao Ziyuan

机构信息

School of Material Science and Engineering, University of Science and Technology Beijing Beijing 100083 China.

Central Research Institute of Building and Construction (CRIBC) Beijing 100088 China

出版信息

RSC Adv. 2023 Mar 14;13(12):8427-8463. doi: 10.1039/d2ra07829e. eCollection 2023 Mar 8.

Abstract

Magnesium alloys have achieved a good balance between biocompatibility and mechanical properties, and have great potential for clinical application, and their performance as implant materials has been continuously improved in recent years. However, a high degradation rate of Mg alloys in a physiological environment remains a major limitation before clinical application. In this review, according to the human body's intake of elements, the current mainstream implanted magnesium alloy system is classified and discussed, and the corrosion mechanism of magnesium alloy and is described, including general corrosion, localized corrosion, pitting corrosion, and degradation of body fluid environment impact The introduction of methods to improve the mechanical properties and biocorrosion resistance of magnesium alloys is divided into two parts: the alloying part mainly discusses the strengthening mechanisms of alloying elements, including grain refinement strengthening, solid solution strengthening, dislocation strengthening and precipitation strengthening ; the surface modification part introduces the ideas and applications of novel materials with excellent properties such as graphene and biomimetic materials in the development of functional coatings. Finally, the existing problems are summarized, and the future development direction is prospected.

摘要

镁合金在生物相容性和力学性能之间取得了良好的平衡,具有巨大的临床应用潜力,近年来其作为植入材料的性能不断提高。然而,镁合金在生理环境中的高降解速率仍然是其临床应用前的主要限制因素。在这篇综述中,根据人体对元素的摄取情况,对当前主流的植入用镁合金体系进行了分类和讨论,并阐述了镁合金的腐蚀机制,包括全面腐蚀、局部腐蚀、点蚀以及体液环境影响下的降解。改善镁合金力学性能和生物耐蚀性的方法介绍分为两部分:合金化部分主要讨论合金元素的强化机制,包括细晶强化、固溶强化、位错强化和析出强化;表面改性部分介绍了石墨烯和仿生材料等具有优异性能的新型材料在功能涂层开发中的思路及应用。最后总结了存在的问题,并对未来的发展方向进行了展望。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/161d/10013130/88c997c9b59f/d2ra07829e-f1.jpg

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