钴催化的芳基锌与 N-氯代胺的亲电胺化反应。
Cobalt-catalyzed electrophilic amination of arylzincs with N-chloroamines.
机构信息
Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique, CNRS, 91128 Palaiseau Cedex, France.
出版信息
Chemistry. 2013 May 10;19(20):6225-9. doi: 10.1002/chem.201300229. Epub 2013 Mar 22.
PMID:23526669
Abstract
Roles reversed: An efficient cobalt-catalyzed electrophilic amination of arylzinc reagents has been achieved. A variety of functionalized arylzincs and N-chloroamines were coupled under mild conditions (see scheme). Both secondary and tertiary arylamines were obtained in moderate to excellent yields.
摘要
角色反转
实现了高效的钴催化芳基锌试剂的亲电胺化反应。在温和条件下，各种官能化的芳基锌试剂和 N-氯代胺发生偶联（见方案）。中等至优异的产率得到了仲芳胺和叔芳胺。
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