Department of Chemistry and Applied Chemistry, Hanyang University, Ansan, Kyunggi-do, 426-791 Korea.
Inorg Chem. 2009 Dec 21;48(24):11507-9. doi: 10.1021/ic901924z.
A twofold interpenetrating polyhedron-based metal-organic framework with high hydrothermal stability was prepared using a rigid and bent C(2)-symmetric ligand containing two 3,5-benzenedicarboxylate units, which have large surface area and high uptake capacities for various gas molecules.
采用刚性和弯曲的 C(2)对称配体,其中包含两个 3,5-苯二甲酸酯单元,具有较大的表面积和对各种气体分子的高吸附能力,制备了具有高热稳定性的双重互穿多面体金属有机骨架。