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银纳米粒子嵌入玻璃纳米纤维的纳米复合材料,通过激光纺丝获得。

Nanocomposites of silver nanoparticles embedded in glass nanofibres obtained by laser spinning.

机构信息

Nanomaterials and Nanotechnology Research Center (CINN-CSIC-UO-PA), Parque Tecnológico de Asturias, Llanera, 33428, Spain.

出版信息

Nanoscale. 2013 May 7;5(9):3948-53. doi: 10.1039/c3nr00638g. Epub 2013 Mar 28.

Abstract

Nanocomposites made of non-woven glass fibres with diameters ranging from tens of nanometers up to several micrometers, containing silver nanoparticles, were successfully fabricated by the laser spinning technique. Pellets of a soda-lime silicate glass containing silver nanoparticles with varying concentrations (5 and 10 wt%) were used as a precursor. The process followed to obtain the silver nanofibres did not agglomerate significantly the metallic nanoparticles, and the average particle size is still lower than 50 nm. This is the first time that glass nanofibres containing silver nanoparticles have been obtained following a process different from electrospinning of a sol-gel, thus avoiding the limitations of this method and opening a new route to composite nanomaterials. Antibacterial efficiency of the nanosilver glass fibres, tested against one of the most common gram negative bacteria, was greater than 99.99% compared to the glass fibres free of silver. The silver nanoparticles are well-dispersed not only on the surface but are also embedded into the uniform nanofibres, which leads to a long lasting durable antimicrobial effect. All these novel characteristics will potentially open up a whole new range of applications.

摘要

由直径从几十纳米到几微米不等的非织造玻璃纤维制成的纳米复合材料,其中含有银纳米粒子,通过激光纺丝技术成功制备。使用含有不同浓度(5 和 10wt%)银纳米粒子的钠钙硅酸盐玻璃颗粒作为前体。获得银纳米纤维的过程并没有使金属纳米粒子明显团聚,并且平均粒径仍低于 50nm。这是首次通过不同于溶胶-凝胶电纺丝的方法获得含有银纳米粒子的玻璃纳米纤维,从而避免了该方法的局限性,并为复合纳米材料开辟了新途径。纳米银玻璃纤维的抗菌效率在测试中对一种最常见的革兰氏阴性菌的抗菌效率大于 99.99%,而不含银的玻璃纤维则没有这种效果。银纳米粒子不仅分布在表面上,而且还嵌入到均匀的纳米纤维中,这导致了持久的耐用的抗菌效果。所有这些新特性都有可能开辟出全新的应用领域。

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