一种从喹啉和异氰酸酯出发，简便、立体选择性和化学选择性合成双环恶唑烷酮的方法。
An expedient stereoselective and chemoselective synthesis of bicyclic oxazolidinones from quinols and isocyanates.
机构信息
Department of Chemistry, Hunter College, 695 Park Avenue, New York, NY 10065, USA.
出版信息
Org Biomol Chem. 2013 May 14;11(18):2939-42. doi: 10.1039/c3ob00047h.
PMID:23536102
Abstract
A mild and efficient synthesis of bicyclic oxazolidinones from quinols and isocyanates, under DBU-mediated conditions at room temperature, is described. The aza-Michael addition to substituted cyclohexadienones is stereoselective and chemoselective.
摘要
描述了在 DBU 介导的条件下，室温下从醌和异氰酸酯温和高效合成双环恶唑烷酮。取代的环己二烯酮的氮杂迈克尔加成具有立体选择性和化学选择性。
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