Department of Chemical and Biological Engineering, University of Wisconsin, Madison, WI, USA.
Annu Rev Chem Biomol Eng. 2013;4:187-209. doi: 10.1146/annurev-chembioeng-061312-103359. Epub 2013 Mar 27.
There is an increasing technological need for a wider array of semiconducting materials that will allow greater control over the physical and electronic structure within multilayer heterostructures. This need has led to an expansion in the range of semiconducting alloys explored and used in new applications. These alloy semiconductors are often complicated by a limited range of miscibility. The current research has focused on the properties, stability, and detailed chemistry required to realize these materials. The use of synthetic conditions that permit the growth of these alloys to be dominated by kinetic rather than mass-transport considerations has allowed many of these nominally unstable materials to be grown and used in device structures. These materials have found important applications within optical communications as emitters and detectors and in solid-state lighting.
对于能够在多层异质结构中实现对物理和电子结构更大程度控制的更广泛的半导体材料,存在日益增长的技术需求。这种需求导致了用于新应用的探索和使用的半导体合金范围的扩大。这些合金半导体通常由于有限的混溶性而变得复杂。目前的研究重点是实现这些材料所需的性质、稳定性和详细化学。使用允许这些合金的生长主要由动力学而不是质量传输因素决定的合成条件,使得许多这些名义上不稳定的材料能够被生长并用于器件结构中。这些材料在光学通信中作为发射器和探测器以及在固态照明中找到了重要的应用。