Institut Parisien de Chimie Moléculaire, IPCM UMR CNRS 7201, Université Pierre et Marie Curie, Paris 6 4 place Jussieu, case 42, 75252 Paris Cedex 05, France.
Chem Commun (Camb). 2013 May 8;49(36):3796-8. doi: 10.1039/c3cc41002a. Epub 2013 Apr 2.
A novel class of luminescent octahedral ruthenium complexes 2-4 displaying a π-bonded quinonoid ligand is described. Remarkably, the presence of this organometallic ligand affects their UV-vis properties and transforms them into panchromatic absorbers. Furthermore, it turns on room temperature NIR emissions.
本文描述了一类新型的八面体钌配合物 2-4，它们具有π键合的醌式配体。值得注意的是，这种有机金属配体的存在影响了它们的紫外可见性质，并将它们转化为全色吸收体。此外，它还开启了室温近红外发射。
