一种与二氧化钛光催化剂复合的多相钯催化剂，用于芳环与乙腈之间的直接 C-C 键形成。
A heterogeneous palladium catalyst hybridised with a titanium dioxide photocatalyst for direct C-C bond formation between an aromatic ring and acetonitrile.
机构信息
Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8603, Japan.
出版信息
Chem Commun (Camb). 2013 May 8;49(36):3793-5. doi: 10.1039/c3cc41068d. Epub 2013 Apr 2.
PMID:23545892
Abstract
A palladium catalyst hybridised with a titanium dioxide photocatalyst can promote cyanomethylation of an aromatic ring by using acetonitrile, where the photocatalyst activates acetonitrile to form a cyanomethyl radical before the C-C bond formation using the palladium catalyst.
摘要
钯催化剂与二氧化钛光催化剂复合，可以使用乙腈促进芳环的氰甲基化，其中光催化剂在使用钯催化剂形成 C-C 键之前激活乙腈形成氰甲基自由基。
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