通过可见光照射下的光氧化还原催化 N-S 键断裂实现对甲苯磺酰胺的脱磺酰化反应。
Desulfonylation of tosyl amides through catalytic photoredox cleavage of N-S bond under visible-light irradiation.
机构信息
Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, PR China.
出版信息
Chem Asian J. 2013 Jun;8(6):1090-4. doi: 10.1002/asia.201300224. Epub 2013 Apr 3.
PMID:23554359
Abstract
All lit up: A novel and efficient desulfonylation method of tosyl amides has been developed by means of visible-light-promoted reductive cleavage of N-S bonds. This method has a broad substrate scope, good functional group tolerance, and excellent yields.
摘要
全点亮
通过可见光促进的 N-S 键还原裂解，开发了一种新颖、高效的对甲苯磺酰胺脱磺酰基方法。该方法具有广泛的底物范围、良好的官能团耐受性和优异的收率。
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