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观点:玻璃化转变。

Perspective: The glass transition.

机构信息

IPhT, CEA/DSM-CNRS/URA 2306, CEA Saclay, F-91191 Gif-sur-Yvette Cedex, France.

出版信息

J Chem Phys. 2013 Mar 28;138(12):12A301. doi: 10.1063/1.4795539.

Abstract

We provide here a brief perspective on the glass transition field. It is an assessment, written from the point of view of theory, of where the field is and where it seems to be heading. We first give an overview of the main phenomenological characteristics, or "stylised facts," of the glass transition problem, i.e., the central observations that a theory of the physics of glass formation should aim to explain in a unified manner. We describe recent developments, with a particular focus on real space properties, including dynamical heterogeneity and facilitation, the search for underlying spatial or structural correlations, and the relation between the thermal glass transition and athermal jamming. We then discuss briefly how competing theories of the glass transition have adapted and evolved to account for such real space issues. We consider in detail two conceptual and methodological approaches put forward recently, that aim to access the fundamental critical phenomenon underlying the glass transition, be it thermodynamic or dynamic in origin, by means of biasing of ensembles, of configurations in the thermodynamic case, or of trajectories in the dynamic case. We end with a short outlook.

摘要

我们在这里简要介绍玻璃化转变领域。这是从理论角度对该领域现状和未来发展方向的评估。我们首先概述玻璃化转变问题的主要现象学特征或“典型事实”,即玻璃形成物理理论应旨在统一解释的核心观测结果。我们描述了最近的发展,特别关注实空间性质,包括动力学非均匀性和促进作用、对潜在空间或结构相关性的探索,以及热玻璃化转变与非热阻塞之间的关系。然后,我们简要讨论了竞争的玻璃化转变理论如何适应和发展以解释这些实空间问题。我们详细考虑了最近提出的两种概念和方法途径,它们旨在通过系综的偏差、热力学情况下的构型或动力学情况下的轨迹,来研究玻璃化转变背后的基本临界现象,无论其起源是热力学还是动力学。最后我们进行了简短的展望。

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