N-杂环卡宾铜催化剂高效催化二氧化碳加氢硅烷化反应。
Highly efficient catalytic hydrosilylation of carbon dioxide by an N-heterocyclic carbene copper catalyst.
机构信息
Organometallic Chemistry Laboratory and Advanced Catalysis Research Group, RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako Saitama 351-0198, Japan.
出版信息
Chem Commun (Camb). 2013 May 25;49(42):4782-4. doi: 10.1039/c3cc41838c.
The N-heterocyclic carbene-copper alkoxide complex [(IPr)Cu(OtBu)] acts as a highly efficient catalyst for the hydrosilylation of carbon dioxide with a hydrosilane. The desired product, silyl formate could be isolated in multigram quantity under solvent free conditions. A copper formate catalyst intermediate was successfully isolated and structurally characterized, thus offering important insight into the mechanistic details.
N-杂环卡宾-铜醇盐复合物[(IPr)Cu(OtBu)]是一种高效的催化剂，可用于二氧化碳与硅烷的氢硅烷化反应。在无溶剂条件下，可分离得到多克级目标产物硅基甲酸酯。成功分离并结构表征了铜甲酸盐催化剂中间体，从而为反应的机理细节提供了重要的见解。
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