Department of Chemical Engineering, KFUPM, Dhahran 31261, Saudi Arabia.
Bioinorg Chem Appl. 2013;2013:458943. doi: 10.1155/2013/458943. Epub 2013 Mar 30.
Water disinfection has attracted the attention of scientists worldwide due to water scarcity. The most significant challenges are determining how to achieve proper disinfection without producing harmful byproducts obtained usually using conventional chemical disinfectants and developing new point-of-use methods for the removal and inactivation of waterborne pathogens. The removal of contaminants and reuse of the treated water would provide significant reductions in cost, time, liabilities, and labour to the industry and result in improved environmental stewardship. The present study demonstrates a new approach for the removal of Escherichia coli (E. coli) from water using as-produced and modified/functionalized carbon nanotubes (CNTs) with 1-octadecanol groups (C18) under the effect of microwave irradiation. Scanning/transmission electron microscopy, thermogravimetric analysis, and FTIR spectroscopy were used to characterise the morphological/structural and thermal properties of CNTs. The 1-octadecanol (C18) functional group was attached to the surface of CNTs via Fischer esterification. The produced CNTs were tested for their efficiency in destroying the pathogenic bacteria (E. coli) in water with and without the effect of microwave radiation. A low removal rate (3-5%) of (E. coli) bacteria was obtained when CNTs alone were used, indicating that CNTs did not cause bacterial cellular death. When combined with microwave radiation, the unmodified CNTs were able to remove up to 98% of bacteria from water, while a higher removal of bacteria (up to 100%) was achieved when CNTs-C18 was used under the same conditions.
由于水资源短缺,水消毒引起了全世界科学家的关注。最大的挑战是确定如何在不产生通常使用传统化学消毒剂获得的有害副产物的情况下进行适当的消毒,并开发新的现场使用方法来去除和灭活水中的病原体。去除污染物和再利用处理后的水将为行业节省大量成本、时间、责任和劳动力,并改善环境管理。本研究展示了一种使用生产的和改性/功能化的带有 1-十八醇基团(C18)的碳纳米管(CNT)在微波辐射作用下从水中去除大肠杆菌(E. coli)的新方法。扫描/透射电子显微镜、热重分析和傅里叶变换红外光谱用于表征 CNT 的形态/结构和热性能。1-十八醇(C18)官能团通过费歇尔酯化法附着在 CNT 的表面。测试了所制备的 CNT 单独使用和在微波辐射作用下对水中致病细菌(E. coli)的破坏效率。当单独使用 CNT 时,获得了 3-5%的(E. coli)细菌的低去除率,这表明 CNT 不会导致细菌细胞死亡。当与微波辐射结合使用时,未经修饰的 CNT 能够从水中去除高达 98%的细菌,而在相同条件下使用 CNT-C18 时,细菌的去除率更高(高达 100%)。