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Sc(OTf)3-catalyzed three-component cyclization of arylamines, β,γ-unsaturated α-ketoesters, and 1,3-dicarbonyl compounds for the synthesis of highly substituted 1,4-dihydropyridines and tetrahydropyridines.三组分环化反应 Sc(OTf)3 催化的三组分环化反应，包括芳胺、β,γ-不饱和α-酮酯和 1,3-二羰基化合物，用于合成高度取代的 1,4-二氢吡啶和四氢吡啶。

J Org Chem. 2013 Jun 7;78(11):5751-5. doi: 10.1021/jo400578m. Epub 2013 May 16.

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Sc(OTf)3-catalyzed indolylation of 1,2-allenic ketones: controlled highly selective synthesis of beta-indolyl-alpha,beta-unsaturetated (E)-enones and beta,beta-bisindolyl ketones.三氟甲磺酸钪催化的1,2-联烯酮的吲哚化反应：β-吲哚基-α,β-不饱和（E）-烯酮和β,β-双吲哚基酮的可控高选择性合成

Org Lett. 2005 Oct 27;7(22):5063-5. doi: 10.1021/ol052073z.

3

Highly diastereoselective synthesis of beta-carboxy-gamma-lactams and their ethyl esters via Sc(OTf)(3)-catalyzed imino Mukaiyama-aldol type reaction of 2,5-bis(trimethylsilyloxy)furan with imines.通过Sc(OTf)(3)催化2,5-双(三甲基硅氧基)呋喃与亚胺的亚氨基Mukaiyama-羟醛型反应高效非对映选择性合成β-羧基-γ-内酰胺及其乙酯。

J Org Chem. 2007 Jun 22;72(13):5016-9. doi: 10.1021/jo070533r. Epub 2007 May 17.

4

Sc(OTf)3-catalyzed dehydrogenative cyclization for synthesis of N-methylacridones.Sc(OTf)3 催化脱氢环化合成 N-甲基吖啶酮。

Org Lett. 2013 Apr 19;15(8):1794-7. doi: 10.1021/ol400371h. Epub 2013 Mar 29.

5

Sc(OTf)3-catalyzed synthesis of indoles and SnCl4-mediated regioselective hydrochlorination of 5-(arylamino)pent-3-yn-2-ones.Sc(OTf)3 催化吲哚合成和 SnCl4 介导的 5-(芳基氨基)戊-3-炔-2-酮区域选择性氯化反应。

J Org Chem. 2011 Oct 21;76(20):8329-35. doi: 10.1021/jo201514q. Epub 2011 Sep 16.

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Sc(OTf)(3)-catalyzed condensation of 2-alkyl-N-tosylaziridine with aldehydes or ketones: an efficient synthesis of 5-alkyl-1,3-oxazolidines.三（三氟甲磺酸）钪催化2-烷基-N-对甲苯磺酰基氮丙啶与醛或酮的缩合反应：5-烷基-1,3-恶唑烷的高效合成

Chem Commun (Camb). 2009 Jul 14(26):3928-30. doi: 10.1039/b902647a. Epub 2009 May 26.

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Synthesis of optically active dihydropyrans from asymmetric [4 + 2] cycloaddition of β,γ-unsaturated α-ketoesters with allenic esters.从不对称的 [4 + 2] 环加成β,γ-不饱和α-酮酯与烯丙酯合成光学活性二氢吡喃。

Org Biomol Chem. 2012 Jun 14;10(22):4355-61. doi: 10.1039/c2ob25475a. Epub 2012 May 3.

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Chiral scandium catalysts for enantioselective Michael reactions of beta-ketoesters.用于β-酮酯对映选择性迈克尔反应的手性钪催化剂。

Chem Asian J. 2006 Jul 17;1(1-2):121-4. doi: 10.1002/asia.200600093.

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Synthesis of a library of 5,6-unsubstituted 1,4-dihydropyridines based on a one-pot 4CR/elimination process and their application to the generation of structurally diverse fused nitrogen heterocycles.基于一锅法4CR/消除反应合成5,6-未取代的1,4-二氢吡啶库及其在生成结构多样的稠合氮杂环中的应用。

J Comb Chem. 2010 Sep 13;12(5):713-22. doi: 10.1021/cc100084b.

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Catalytic enantioselective Hosomi-Sakurai conjugate allylation of cyclic unsaturated ketoesters.环状不饱和酮酯的催化对映选择性保米-樱井共轭烯丙基化反应

Angew Chem Int Ed Engl. 2008;47(27):5049-51. doi: 10.1002/anie.200800628.

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三组分环化反应 Sc(OTf)3 催化的三组分环化反应，包括芳胺、β,γ-不饱和α-酮酯和 1,3-二羰基化合物，用于合成高度取代的 1,4-二氢吡啶和四氢吡啶。

Sc(OTf)3-catalyzed three-component cyclization of arylamines, β,γ-unsaturated α-ketoesters, and 1,3-dicarbonyl compounds for the synthesis of highly substituted 1,4-dihydropyridines and tetrahydropyridines.

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