通过非共价两亲性折叠体的分级自组装形成的混合给体-受体电荷转移堆积。
Mixed donor-acceptor charge-transfer stacks formed via hierarchical self-assembly of a non-covalent amphiphilic foldamer.
机构信息
Supramolecular Chemistry Laboratory, New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064, India.
出版信息
Chem Commun (Camb). 2013 Jun 7;49(45):5174-6. doi: 10.1039/c3cc41911h.
PMID:23628867
Abstract
A non-covalent, amphiphilic foldamer design leads to an efficient charge-transfer complex between dipyrene (donor) and naphthalene diimide (acceptor) derivatives, which further self-assembles into one-dimensional nanofibers with an alternate (mixed) donor-acceptor arrangement.
摘要
一种非共价的、两亲性的折叠体设计导致了二吡咯（供体）和萘二酰亚胺（受体）衍生物之间有效的电荷转移复合物的形成，该复合物进一步自组装成具有交替（混合）供体-受体排列的一维纳米纤维。
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