State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, China.
Dalton Trans. 2013 Jun 21;42(23):8183-7. doi: 10.1039/c3dt50687h. Epub 2013 Apr 30.
The d(10)-metal-oxo clusters connected by the asymmetric tricarboxylate and linear neutral ligands give rise to two novel high-connected MOFs. They feature the highest (3,16)- and (3,8)-connected three-dimensional frameworks based on cube-like octanuclear [Zn8(μ2-OH)4(CO2)12] clusters and butterfly-like tetranuclear [Cd4(μ3-OH)2(CO2)6] clusters as the secondary building units, respectively.
不对称三羧酸和线性中性配体连接的 d(10)-金属氧簇形成了两个新型的高连接 MOF。它们具有最高的（3,16）和（3,8）连接的三维骨架，分别基于立方八核[Zn8(μ2-OH)4(CO2)12]簇和蝶形四核[Cd4(μ3-OH)2(CO2)6]簇作为次级构筑单元。
