两个基于 d10 金属簇的高连接金属有机骨架：合成、结构拓扑和发光性质。
Two high-connected metal-organic frameworks based on d10-metal clusters: syntheses, structural topologies and luminescent properties.
机构信息
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, China.
出版信息
Dalton Trans. 2013 Jun 21;42(23):8183-7. doi: 10.1039/c3dt50687h. Epub 2013 Apr 30.
The d(10)-metal-oxo clusters connected by the asymmetric tricarboxylate and linear neutral ligands give rise to two novel high-connected MOFs. They feature the highest (3,16)- and (3,8)-connected three-dimensional frameworks based on cube-like octanuclear [Zn8(μ2-OH)4(CO2)12] clusters and butterfly-like tetranuclear [Cd4(μ3-OH)2(CO2)6] clusters as the secondary building units, respectively.
不对称三羧酸和线性中性配体连接的 d(10)-金属氧簇形成了两个新型的高连接 MOF。它们具有最高的（3,16）和（3,8）连接的三维骨架，分别基于立方八核[Zn8(μ2-OH)4(CO2)12]簇和蝶形四核[Cd4(μ3-OH)2(CO2)6]簇作为次级构筑单元。
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