• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

链状聚[[[二水合-（四甲基乙二胺-κ(2) N,N'）镍（II）]-μ-硫酸根-κ(2) O:O']一水合物]

catena-Poly[[[diaqua-(tetra-methyl-ethylenediamine-κ(2) N,N')nickel(II)]-μ-sulfato-κ(2) O:O'] monohydrate].

作者信息

Schmidt Guntram, Merzweiler Kurt

机构信息

Institut für Chemie, Naturwissenschaftliche Fakultät II, Martin-Luther-Universität Halle-Wittenberg, Kurt-Mothes-Strasse 2, 06120 Halle (Saale), Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 13;69(Pt 4):m197. doi: 10.1107/S1600536813006557. Print 2013 Apr 1.

DOI:10.1107/S1600536813006557
PMID:23633997
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3629479/
Abstract

The title compound, {[Ni(SO4)(C6H16N2)(H2O)2]·H2O} n , contains a Ni(II) atom that is coordinated nearly octa-hedrally by a chelating tetra-ethyl-enediamine (tmeda) ligand, two water mol-ecules in a cis arrangement and two O atoms of two sulfate anions in a trans arrangement. The sulfate anions act as μ2-bridging ligands leading to a chain structure of alternating NiO4N2 octa-hedra and SO4 tetra-hedra parallel to [001]. The polymeric chains are linked by O-H⋯O hydrogen bonds between coordinating water mol-ecules and sulfate anions to give double strands. There is a lattice water mol-ecule which is also involved in O-H⋯O hydrogen bonding between adjacent [Ni(SO4)(tmeda)(H2O)2] chains.

摘要

标题化合物{[Ni(SO₄)(C₆H₁₆N₂)(H₂O)₂]·H₂O}ₙ包含一个Ni(II)原子，该原子由螯合的四乙二胺（tmeda）配体、两个呈顺式排列的水分子以及两个呈反式排列的硫酸根阴离子的两个O原子近似八面体配位。硫酸根阴离子作为μ₂-桥联配体，导致形成平行于[001]的由交替的NiO₄N₂八面体和SO₄四面体组成的链状结构。聚合物链通过配位水分子与硫酸根阴离子之间的O—H⋯O氢键相连形成双链。存在一个晶格水分子，它也参与相邻[Ni(SO₄)(tmeda)(H₂O)₂]链之间的O—H⋯O氢键作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e645/3629479/4d034fce9df8/e-69-0m197-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e645/3629479/0e3e00e64ffa/e-69-0m197-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e645/3629479/f5d1a35695d9/e-69-0m197-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e645/3629479/4d034fce9df8/e-69-0m197-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e645/3629479/0e3e00e64ffa/e-69-0m197-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e645/3629479/f5d1a35695d9/e-69-0m197-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e645/3629479/4d034fce9df8/e-69-0m197-fig3.jpg

相似文献

1
catena-Poly[[[diaqua-(tetra-methyl-ethylenediamine-κ(2) N,N')nickel(II)]-μ-sulfato-κ(2) O:O'] monohydrate].链状聚[[[二水合-（四甲基乙二胺-κ(2) N,N'）镍（II）]-μ-硫酸根-κ(2) O:O']一水合物]
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 13;69(Pt 4):m197. doi: 10.1107/S1600536813006557. Print 2013 Apr 1.
2
Poly[aqua-(μ2-4,4'-bipyridine-κ(2) N:N')(ethane-1,2-diol-κO)(μ2-sulfato-κ(2) O:O')nickel(II)].聚[水合-（μ2-4,4'-联吡啶-κ(2) N:N'）（1,2-乙二醇-κO）（μ2-硫酸根-κ(2) O:O'）镍（II）]
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 1;69(Pt 3):m154-5. doi: 10.1107/S1600536813003772. Epub 2013 Feb 16.
3
catena-Poly[[diaqua-bis-(2-ethyl-1H-imidazole-κN(3))cadmium]-μ-sulfato-κ(2)O:O'].链状聚[[二水合双（2-乙基-1H-咪唑-κN(3)）镉]-μ-硫酸根-κ(2)O:O']
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m655. doi: 10.1107/S1600536812017059. Epub 2012 Apr 21.
4
Crystal structures of tetra-methyl-ammonium (2,2'-bi-pyridine)-tetra-cyanidoferrate(III) trihydrate and poly[[(2,2'-bi-pyridine-κ(2) N,N')di-μ2-cyanido-dicyanido(μ-ethyl-enedi-amine)(ethyl-enedi-amine-κ(2) N,N')-cadmium(II)iron(II)] monohydrate].四甲基铵（2,2'-联吡啶）四氰基铁（III）三水合物和聚[[(2,2'-联吡啶-κ(2) N,N')二-μ2-氰基-二氰基(μ-乙二胺)(乙二胺-κ(2) N,N')-镉(II)铁(II)]]的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Apr 29;72(Pt 5):741-6. doi: 10.1107/S2056989016006848. eCollection 2016 May 1.
5
Aqua-{2-(pyridin-2-yl)-N-[(pyridin-2-yl)methyl-idene]ethanamine-κ(3) N,N',N''}(sulfato-κ(2) O,O')copper(II) tetra-hydrate.水合-{2-(吡啶-2-基)-N-[(吡啶-2-基亚甲基]乙胺-κ(3)N,N',N''}(硫酸根-κ(2)O,O')铜(II)四水合物
Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m24-5. doi: 10.1107/S1600536812049380. Epub 2012 Dec 8.
6
Poly[diaqua-bis-(μ-4,4'-bipyridine-κ(2) N:N')bis-(ethane-1,2-diol-κO)bis(μ-sulfato-κ(2) O:O')dicobalt(II)].聚[二水合-双-(μ-4,4'-联吡啶-κ(2) N:N')双-(乙二醇-κO)双(μ-硫酸根-κ(2) O:O')二钴(II)]
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 16;69(Pt 4):m207-8. doi: 10.1107/S1600536813006685. Print 2013 Apr 1.
7
catena-Poly[[[diaqua-(1,10-phenanthroline-κ(2)N,N')zinc]-μ-4,4'-bipyridine-κ(2)N:N'] dinitrate 4,4'-bipyridine hemisolvate monohydrate].链状聚[[[二水合-(1,10-菲咯啉-κ(2)N,N')锌]-μ-4,4'-联吡啶-κ(2)N:N']二硝酸酯 4,4'-联吡啶半溶剂合物一水合物]
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1222-3. doi: 10.1107/S1600536812036318. Epub 2012 Aug 31.
8
Crystal structure of poly[di-aqua-(μ2-benzene-1,4-di-carboxyl-ato-κ(2) O (1):O (4))(μ2-benzene-1,4-di-carboxyl-ato-κ(4) O (1),O (1'):O (4),O (4'))bis-(μ2-3,3',5,5'-tetra-methyl-4,4'-bi-pyrazole-κ(2) N:N')dinickel(II)].聚[二水合-(μ2-苯-1,4-二羧酸根-κ(2)O(1):O(4))(μ2-苯-1,4-二羧酸根-κ(4)O(1),O(1'):O(4),O(4'))双-(μ2-3,3',5,5'-四甲基-4,4'-联吡唑-κ(2)N:N')二镍(II)]的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 May 7;71(Pt 6):m127-8. doi: 10.1107/S2056989015008415. eCollection 2015 Jun 1.
9
Crystal structure of catena-poly[[tetra-aqua-magnesium]-μ-(di-hydrogen hypodiphosphato)-κ(2) O:O'].链状聚[[四水合镁]-μ-(二氢连二磷酸根)-κ(2) O:O']的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jun 27;71(Pt 7):867-9. doi: 10.1107/S2056989015012037. eCollection 2015 Jul 1.
10
catena-Poly[[diaqua-bis-(3-methyl-pyridine-κN)cobalt(II)]-μ-sulfato-κO:O'].链状聚[[二水合双-(3-甲基吡啶-κN)钴(II)]-μ-硫酸根-κO:O']
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1065-6. doi: 10.1107/S1600536811025815. Epub 2011 Jul 9.

本文引用的文献

1
A novel tridentate coordination mode for the carbonatonickel system exhibited in an unusual hexanuclear nickel(II) mu3-carbonato-bridged complex.一种新颖的三齿配位模式在一种不寻常的六核镍（II）μ3-碳酸桥连配合物中被展示出来，该配合物涉及碳酸根镍(II)配合物。
Dalton Trans. 2009 Nov 14(42):9153-6. doi: 10.1039/b912612k. Epub 2009 Sep 2.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Amine-templated one-dimensional metal sulfates including a mixed-valent Fe compound with a half-kagome structure.
胺模板化的一维金属硫酸盐，包括一种具有半 Kagome 结构的混合价态铁化合物。
Chem Asian J. 2006 Nov 20;1(5):742-50. doi: 10.1002/asia.200600083.