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链状聚[[[二水合-(1,10-菲咯啉-κ(2)N,N')锌]-μ-4,4'-联吡啶-κ(2)N:N']二硝酸酯 4,4'-联吡啶半溶剂合物一水合物]

catena-Poly[[[diaqua-(1,10-phenanthroline-κ(2)N,N')zinc]-μ-4,4'-bipyridine-κ(2)N:N'] dinitrate 4,4'-bipyridine hemisolvate monohydrate].

作者信息

Xu Shan, Dai Yong-Cheng, Qiu Qi-Ming, Jin Qiong-Hua, Zhang Cun-Lin

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1222-3. doi: 10.1107/S1600536812036318. Epub 2012 Aug 31.

DOI:10.1107/S1600536812036318
PMID:22969502
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3435629/
Abstract

In the title compound, Zn(C(10)H(8)N(2))(C(12)H(8)N(2))(H(2)O)(2)(2)·0.5C(10)H(8)N(2)·H(2)O, the Zn(II) atom is coordinated in a distorted octa-hedral geometry by two N atoms from two 4,4'-bipyridine (4,4'-bipy) ligands, two N atoms from a chelating 1,10-phenanthroline ligand and two O atoms from two mutually cis water mol-ecules. The 4,4'-bipy ligands bridge the Zn(II) atoms into a chain structure along [100]. The uncoordinated 4,4'-bipy mol-ecule lies on an inversion center. O-H⋯O and O-H⋯N hydrogen bonds connect the cationic chains, the nitrate anions, the uncoordinated 4,4'-bipy mol-ecules and the water mol-ecules into tow-dimensional networks.

摘要

在标题化合物Zn(C₁₀H₈N₂)(C₁₂H₈N₂)(H₂O)₂₂·0.5C₁₀H₈N₂·H₂O中，Zn(II)原子由两个4,4'-联吡啶（4,4'-bipy）配体的两个N原子、一个螯合的1,10-菲咯啉配体的两个N原子以及两个相互呈顺式的水分子的两个O原子以扭曲的八面体几何构型配位。4,4'-bipy配体将Zn(II)原子沿[100]桥连形成链状结构。未配位的4,4'-bipy分子位于一个对称中心上。O—H⋯O和O—H⋯N氢键将阳离子链、硝酸根阴离子、未配位的4,4'-bipy分子和水分子连接成二维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de75/3435629/4cc9b6b02ffa/e-68-m1222-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de75/3435629/8ff84d42b307/e-68-m1222-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de75/3435629/4cc9b6b02ffa/e-68-m1222-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de75/3435629/8ff84d42b307/e-68-m1222-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de75/3435629/4cc9b6b02ffa/e-68-m1222-fig2.jpg

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