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3,9-Dimethyl-2,3-dihydro-spiro-[carb-az-ole-1,2'-[1,3]dithio-lan]-4(9H)-one.

作者信息

Gülle Sibel, Caylak Delibaş Nagihan, Ergün Yavuz, Hökelek Tuncer

机构信息

Celal Bayar University, Faculty of Arts and Sciences, Department of Chemistry, 45030 Muradiye, Manisa, Turkey.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 28;69(Pt 4):o598-9. doi: 10.1107/S1600536813007873. Print 2013 Apr 1.

Abstract

The title compound, C16H17NOS2, consists of a carbazole skeleton with methyl and dithiol-ane groups as substituents. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.02 (11)°. The cyclo-hexenone ring has a twisted conformation, while the dithiol-ane ring adopts an envelope conformation with one of the CH2 C atoms at the flap. In the crystal, weak C-H⋯O hydrogen bonds link the mol-ecules into supra-molecular chains nearly parallel to the c axis. These hydrogen bonds together with weak C-H⋯π inter-actions link the molecules into a three-dimensional supramolecular network.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90b2/3629639/3c1ba870079e/e-69-0o598-fig1.jpg

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