雷尼镍在室温下催化乙酰丙酸酯向 γ-戊内酯的转移加氢。
RANEY® Ni catalyzed transfer hydrogenation of levulinate esters to γ-valerolactone at room temperature.
机构信息
Anhui Province Key Laboratory of Biomass Clean Energy, Department of Chemistry, University of Science and Technology of China, Hefei 230026, PR China.
出版信息
Chem Commun (Camb). 2013 Jun 11;49(46):5328-30. doi: 10.1039/c3cc40980e.
PMID:23648801
Abstract
A catalytic transfer hydrogenation process was developed for the production of γ-valerolactone (GVL) from ethyl levulinate (EL) and a H-donor at room temperature. Ethyl levulinate was almost quantitatively converted to γ-valerolactone. Further, a two step process for producing GVL from biomass derived platform molecules was also reported.
摘要
开发了一种在室温下从乙酰丙酸乙酯（EL）和供氢体生产γ-戊内酯（GVL）的催化转移氢化工艺。乙酰丙酸乙酯几乎定量转化为γ-戊内酯。此外，还报道了从生物质衍生的平台分子生产 GVL 的两步法工艺。
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