区域和化学选择性钯催化烯丙基化反应：钯纳米粒子的显著影响。

Regio- and chemoselective palladium-catalyzed benzylallylation of activated olefins: the remarkable effect of palladium nanoparticles.

机构信息

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China.

出版信息

Org Biomol Chem. 2013 Jun 28;11(24):4016-24. doi: 10.1039/c3ob40487k.

Abstract

The palladium-catalyzed three-component reactions of benzyl halides, activated olefins, and allyltributylstannane were successfully conducted to produce the corresponding benzylallylation products in satisfactory to high yields. The benzylallylation reaction proceeded smoothly under mild conditions in the presence of palladium nanoparticles in tetrahydrofuran.

摘要

钯催化的苄基卤、活化烯烃和烯丙基三丁基锡的三组分反应成功进行，在四氢呋喃中钯纳米粒子的存在下，以令人满意至高产率得到相应的苄基烯丙基化产物。