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在不锈钢电极上进行多壁碳纳米管的电泳沉积,用于沉淀微生物燃料电池。

Electrophoretic deposition of multi-walled carbon nanotube on a stainless steel electrode for use in sediment microbial fuel cells.

机构信息

Institute of Joint Bioenergy, College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, No. 5 Xinmofan Road, Nanjing 210009, People's Republic of China.

出版信息

Appl Biochem Biotechnol. 2013 Jul;170(5):1241-50. doi: 10.1007/s12010-013-0274-3. Epub 2013 May 9.

Abstract

Sediment microbial fuel cells (SMFCs) could be used as power sources and one type of new technology for the removal of organic matters in sediments. In order to improve electrode materials and enhance their effect on the performance, we deposited multi-walled carbon nanotube (MWNT) on stainless steel net (SSN). Electrophoretic deposition technique as a method with low cost, process simplicity, and thickness control was used for this electrode modification and produced this novel SSN-MWNT electrode. The performances of SMFCs with SSN-MWNT as electrode were investigated. The results showed that the maximum power density of SMFC with SSN-MWNT cathode was 31.6 mW m(-2), which was 3.2 times that of SMFC with an uncoated stainless steel cathode. However, no significant increase in the maximum power density of SMFC with SSN-MWNT anode was detected. Further electrochemical analysis showed that when SSN-MWNT was used as the cathode, the cathodic electrochemical activity and oxygen reduction rate were significantly improved. This study demonstrates that the electrophoretic deposition of carbon nanotubes on conductive substrate can be applied for improving the performance of SMFC.

摘要

沉积物微生物燃料电池 (SMFC) 可用作电源和一种去除沉积物中有机物的新技术。为了改进电极材料并增强其对性能的影响,我们在不锈钢网上沉积了多壁碳纳米管 (MWNT)。电泳沉积技术是一种成本低、工艺简单、厚度可控的方法,用于这种电极修饰,并产生了这种新型 SSN-MWNT 电极。研究了以 SSN-MWNT 为电极的 SMFC 的性能。结果表明,以 SSN-MWNT 为阴极的 SMFC 的最大功率密度为 31.6 mW m(-2),是未涂覆不锈钢阴极的 SMFC 的 3.2 倍。然而,并未检测到以 SSN-MWNT 为阳极的 SMFC 的最大功率密度有明显增加。进一步的电化学分析表明,当 SSN-MWNT 用作阴极时,阴极电化学活性和氧还原速率得到显著提高。本研究表明,在导电基底上电泳沉积碳纳米管可用于提高 SMFC 的性能。

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