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电泳沉积法制备的碳纳米管修饰阴极对沉积型微生物燃料电池性能的影响

Effect of carbon nanotube modified cathode by electrophoretic deposition method on the performance of sediment microbial fuel cells.

作者信息

Zhu Dawei, Wang De-Bin, Song Tian-Shun, Guo Ting, Ouyang Pingkai, Wei Ping, Xie Jingjing

机构信息

State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, 211816, People's Republic of China.

出版信息

Biotechnol Lett. 2015 Jan;37(1):101-7. doi: 10.1007/s10529-014-1671-6. Epub 2014 Sep 26.

Abstract

A multi-walled, carbon nanotube (MWNT)-modified graphite felt (GF) cathode was fabricated to improve the performance of sediment microbial fuel cells (SMFC). Three types of MWNT-modified GF cathodes were prepared by different electrophoretic deposition (EPD) times. Maximum power density of SMFC with MWNT-GF*** cathode at 60 min EPD was 215 ± 9.9 mW m(-2). This was 1.6 times that of SMFC with a bare GF cathode. Cyclic voltammetry and the amount of biomass showed that biomass density and electrochemical activity increased as the electrophoretic deposition time extended. Therefore the electrode possesses the highest catalytic behavior toward O2 reduction reaction. This simple process of carbon nanotube modification of a cathode by EPD can serve as an effective technique to improve the performance of SMFC.

摘要

为提高沉积物微生物燃料电池(SMFC)的性能,制备了一种多壁碳纳米管(MWNT)修饰的石墨毡(GF)阴极。通过不同的电泳沉积(EPD)时间制备了三种类型的MWNT修饰的GF阴极。在EPD时间为60分钟时,带有MWNT-GF***阴极的SMFC的最大功率密度为215±9.9 mW m(-2)。这是带有裸GF阴极的SMFC的1.6倍。循环伏安法和生物量表明,随着电泳沉积时间的延长,生物量密度和电化学活性增加。因此,该电极对O2还原反应具有最高的催化行为。这种通过EPD对阴极进行碳纳米管修饰的简单过程可作为提高SMFC性能的有效技术。

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