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具有吡啶四唑和膦配体的中性铜（I）配合物的优异发光。

Outstanding luminescence from neutral copper(I) complexes with pyridyl-tetrazolate and phosphine ligands.

机构信息

Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131 Karlsruhe, Germany.

出版信息

Chem Commun (Camb). 2013 Jul 25;49(58):6501-3. doi: 10.1039/c3cc42280a. Epub 2013 May 9.

DOI:10.1039/c3cc42280a
PMID:23660875
Abstract

Strongly luminescent, neutral copper(I) complexes bearing 5-(2-pyridyl)tetrazolate and various phosphine ligands were synthesized. While the cationic copper(I) precursors 1b-4b do not exceed photoluminescence quantum yields (PLQY) of 4-46%, the neutral complexes 1a-4a show PLQYs of up to 89%.

摘要

合成了强发光的中性铜（I）配合物，其配体为 5-(2-吡啶基)四唑和各种膦配体。虽然阳离子铜（I）前体 1b-4b 的光致发光量子产率（PLQY）不超过 4-46%，但中性配合物 1a-4a 的 PLQY 高达 89%。

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