Département de Chimie, Université de Sherbrooke, 2550 Boulevard de l'Université, Sherbrooke, Québec, Canada J1K 2R1.
Chem Commun (Camb). 2013 Jun 21;49(49):5544-6. doi: 10.1039/c3cc42634c.
Despite conjugation and downhill manifolds in [Ir]-[Pt]-[ZnTPP] ([ZnTPP] = (tetraphenylporphyrin)zinc(II), [Ir] = bis(phenylpyridinato)(bipyridine)iridium(III), [Pt] = trans-C≡CPt(PBu3)2-C≡C), essentially no T1[Ir] → S1/T1[ZnTTP] energy transfer occurs.
尽管[Ir]-[Pt]-[ZnTPP]([ZnTPP] = (四苯基卟啉)锌(II),[Ir] = 双(苯并吡啶基)(联吡啶)铱(III),[Pt] = 顺式-C≡CPt(PBu3)2-C≡C)发生了共轭和下坡模式,但基本上没有 T1[Ir]→S1/T1[ZnTTP]能量转移发生。