Sun Yan, Cao Xiaoan, Liu Yonghui, Wang Nijing, He Ruiwen
Environmental Science and Engineering Institute, Guangzhou University, 510006, Guangzhou, China.
Luminescence. 2014 Mar;29(2):122-6. doi: 10.1002/bio.2514. Epub 2013 May 17.
We present a sensitive and quick way to determine benzene, toluene and dimethylbenzene (BTEX) in air, applying a cataluminescence (CTL) sensor based on a nano-sized composite material, γ-Al2O3/PtO2. The factors that affect the sensor's performance were studied, including the sensing material, temperature, rate of air carrier and wavelength. It was shown that when Pt accounted for 0.2% of the sensing material, the rate of the air carrier that carries target gas was 450 mL/min, the determination wavelength was 400 nm and temperature was 236 °C, this sensor showed the best CTL intensity to BTEX. In addition, the CTL intensity had a high linear relation with the concentration of BTEX, with a linear range from 0.5 to 100 mL/m(3), and a detection limit 0.22 mL/m(3). This nano-sized material had a quick response within 1.5 s, short recovery time within 1 min and a long lifetime, showing good potential for a variety of applications.
我们展示了一种灵敏且快速的方法来测定空气中的苯、甲苯和二甲苯(BTEX),该方法采用了基于纳米复合材料γ-Al2O3/PtO2的催化发光(CTL)传感器。研究了影响传感器性能的因素,包括传感材料、温度、载气速率和波长。结果表明,当Pt在传感材料中占0.2%,载带目标气体的载气速率为450 mL/min,测定波长为400 nm且温度为236 °C时,该传感器对BTEX表现出最佳的CTL强度。此外,CTL强度与BTEX浓度具有高度线性关系,线性范围为0.5至100 mL/m³,检测限为0.22 mL/m³。这种纳米材料响应迅速,在1.5秒内即可完成,恢复时间短,在1分钟内即可恢复,且使用寿命长,显示出在各种应用中的良好潜力。