Qin Yu-Sheng, Zhan Shao-Jun, Yu Hua, Tu Shi-Hua, Wang Zheng-Yin
College of Resources and Environment, Southwest University, Chongqing 400716, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2013 Feb;33(2):476-80.
Adopting atomic absorption spectrometry (novAA400), the present study investigated the distribution characteristics of soil cadmium (Cd) in different textured paddy soil profiles under rice-wheat rotation and its correlation with Cd uptake by rice and wheat in Chengdu Plain through repeatedly taking soil and plant samples at the fixed sites in the field. The results revealed that Cd in the paddy soil profiles was mainly concentrated at the plough layer (0-15 cm) that obviously featured 'Cd accumulates towards the rooting layer'. Soil total Cd and available Cd (1 mol x L(-1) MgCl2 extraction) in the profile declined with soil depths and its average values at 30-45 cm only accounted for 47.60% and 39.49% of those at 0-15 cm. The potential downward movement of Cd in the different textured soil profiles was observed as sandy loam > heavy loam > loam. There was no significant correlation between soil pH and available Cd(r = - 0.46) at 0-15 cm soil depth, while significantly negative correlations between soil pH and available Cd were observed at 15-30 cm (r = -0.78) and 30-45 cm (r = -0.86). The results further demonstrated that the Cd contents in either grain or straw of rice and wheat were not well correlated with soil total Cd at any soil depth (r = -0.092-0.383 for rice and r = 0.174-0.424 for wheat), but significantly correlated with soil available Cd at 0-15 cm and at 15-30 cm (r = 0.766*-0.953**) despite insignificant correlation at 30-45 cm (r = 0.526-0.584). It is strongly suggested that the soil available Cd can be used as a better criterion than the total soil Cd to rate Cd contaminated soils in relation to safety of agricultural products.
本研究采用原子吸收光谱法(novAA400),通过在田间固定位点反复采集土壤和植物样本,研究了成都平原稻麦轮作下不同质地水稻土剖面中土壤镉(Cd)的分布特征及其与水稻和小麦吸收Cd的相关性。结果表明,水稻土剖面中的Cd主要集中在耕作层(0 - 15厘米),明显呈现出“Cd向生根层积累”的特征。剖面中土壤总Cd和有效Cd(1摩尔×升(-1)MgCl2提取)随土壤深度下降,其在30 - 45厘米处的平均值仅分别占0 - 15厘米处的47.60%和39.49%。不同质地土壤剖面中Cd的潜在向下移动情况为砂壤土>重壤土>壤土。在0 - 15厘米土壤深度处,土壤pH与有效Cd之间无显著相关性(r = - 0.46),而在15 - 30厘米(r = -0.78)和30 - 45厘米(r = -0.86)处观察到土壤pH与有效Cd之间存在显著负相关。结果进一步表明,水稻和小麦籽粒或秸秆中的Cd含量与任何土壤深度的土壤总Cd均无良好相关性(水稻r = -0.092 - 0.383,小麦r = 0.174 - 0.424),但与0 - 15厘米和15 - 30厘米处的土壤有效Cd显著相关(r = 0.766* - 0.953**),尽管在30 - 45厘米处相关性不显著(r = 0.526 - 0.584)。强烈建议,相对于土壤总Cd而言,土壤有效Cd可作为评价与农产品安全性相关的Cd污染土壤的更好标准。