Department of Chemical, Energy and Environmental Engineering, Kansai University, Suita-shi, Osaka 564-8680, Japan.
Chem Commun (Camb). 2013 Sep 18;49(72):7884-6. doi: 10.1039/c3cc43028f. Epub 2013 May 28.
Mechanochemical dry conversion that only uses zinc oxide and an imidazole ligand proved to be effective and reliable for fabrication of a zeolitic imidazolate framework with a polycrystalline grain boundary and a core-shell structure. The zinc oxide crystals are converted into a zeolitic imidazolate framework to a depth of approx. 10 nm below the surface.
仅使用氧化锌和咪唑配体的机械化学干法转化被证明是有效的和可靠的，可用于制造具有多晶界和核壳结构的沸石咪唑骨架。氧化锌晶体在表面以下约 10nm 的深度转化为沸石咪唑骨架。
