镧系配位聚合物在磁场下冷却、弛豫并发出荧光。
Lanthanide based coordination polymers chill, relax under magnetic field and also fluoresce.
机构信息
Department of Chemistry, IISER Bhopal, Bhopal 462023, MP, India.
出版信息
Dalton Trans. 2013 Jul 21;42(27):9813-7. doi: 10.1039/c3dt51195b. Epub 2013 May 29.
PMID:23715412
Abstract
Three lanthanide one-dimensional coordination polymers, obtained using Ln(3+) salts and croconate dianion, were structurally characterized. Magnetic studies reveal that the gadolinium analogue exhibits a large magnetocaloric effect while single-molecule magnet behaviour is observed in the dysprosium analogue.
摘要
三种镧系一维配位聚合物，通过 Ln(3+)盐和重铬酸二阴离子得到，其结构特征得到了研究。磁性研究表明，钆类似物表现出较大的磁热效应，而镝类似物则表现出单分子磁体行为。
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