Department of Chemistry, Indian Institute of Science Education and Research, Pune 411021, India.
Chem Commun (Camb). 2013 Jul 11;49(54):6060-2. doi: 10.1039/c3cc42683a.
The oxidative cyclization of aromatic and heteroaromatic nitriles with alkynes in the presence of a catalytic amount of [{RuCl2(p-cymene)}2], Cu(OAc)2·H2O and KPF6 in acetic acid under air gave isoquinolones in good to excellent yields.
在醋酸中,在催化量的 [{RuCl2(p-cymene)}2]、Cu(OAc)2·H2O 和 KPF6 的存在下,芳族和杂芳族腈与炔烃在空气中进行氧化环化反应,以良好至优异的收率得到异喹啉酮。