School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.
Chem Commun (Camb). 2013 Jul 28;49(59):6611-3. doi: 10.1039/c3cc42326c.
Regioselective synthesis of polysubstituted benzofurans using a copper catalyst and molecular oxygen from phenols and alkynes in a one-pot procedure has been reported. The transformation consists of a sequential nucleophilic addition of phenols to alkynes and oxidative cyclization. A wide variety of phenols and alkynes can be used in the same manner.
本文报道了一种使用铜催化剂和分子氧，从酚类化合物和炔烃一锅法制备多取代苯并呋喃的区域选择性合成方法。该转化包括酚类化合物对炔烃的顺序亲核加成和氧化环化。多种酚类化合物和炔烃可以以相同的方式使用。
