• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

链状聚[[四水合镉]-μ-5,5'-(1,4-亚苯基)二(四唑-2-基)-κ(2) N(2):N(2')]

catena-Poly[[tetra-aqua-cadmium]-μ-5,5'-(1,4-phenyl-ene)di(tetra-zol-2-ido)-κ(2) N (2):N (2')].

作者信息

Dang Qinqin, Caiyun Han

机构信息

School of Chemistry & Material Science, Shanxi Normal University, Linfen 041004, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 20;69(Pt 5):m283. doi: 10.1107/S1600536813010441. Print 2013 May 1.

DOI:10.1107/S1600536813010441
PMID:23723784
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3647818/
Abstract

In the title compound, [Cd(C8H4N8)(H2O)4] n , 5,5'-(1,4-phenyl-ene)di(tetra-zol-2-ide) (L) ligands bridge Cd(II) atoms into polymeric chains along [201]. The Cd(II) atom is situated on an inversion centre and is coordinated by two N atoms from two L ligands and by four water O atoms in a distorted octa-hedral geometry. In the L ligand, the benzene ring resides on an inversion centre and the tetra-zole rings are twisted from its plane by 22.3 (1)°. An extensive hydrogen-bonding network formed by classical O-H⋯N and O-H⋯O inter-actions consolidates the crystal packing, linking the poymeric chains into a three-dimensional structure.

摘要

在标题化合物[Cd(C₈H₄N₈)(H₂O)₄]ₙ中，5,5'-(1,4-亚苯基)二(四唑-2-基)（L）配体将Cd(II)原子沿[201]方向桥连形成聚合物链。Cd(II)原子位于一个对称中心上，由来自两个L配体的两个N原子和四个水分子的O原子配位，呈扭曲的八面体几何构型。在L配体中，苯环位于一个对称中心上，四唑环与苯环平面扭转了22.3 (1)°。由经典的O—H⋯N和O—H⋯O相互作用形成的广泛氢键网络巩固了晶体堆积，将聚合物链连接成三维结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cf0/3647818/32bd5fa65ca6/e-69-0m283-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cf0/3647818/32bd5fa65ca6/e-69-0m283-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5cf0/3647818/32bd5fa65ca6/e-69-0m283-fig1.jpg

相似文献

1
catena-Poly[[tetra-aqua-cadmium]-μ-5,5'-(1,4-phenyl-ene)di(tetra-zol-2-ido)-κ(2) N (2):N (2')].链状聚[[四水合镉]-μ-5,5'-(1,4-亚苯基)二(四唑-2-基)-κ(2) N(2):N(2')]
Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 20;69(Pt 5):m283. doi: 10.1107/S1600536813010441. Print 2013 May 1.
2
catena-Poly[(trans-diaqua-cadmium)-bis-{μ-5-[4-(1H-imidazol-1-yl)phen-yl]tetra-zol-1-ido}].链状聚[（反式-二水合镉）-双-{μ-5-[4-(1H-咪唑-1-基)苯基]四唑-1-基}]
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m585-6. doi: 10.1107/S1600536812014626. Epub 2012 Apr 13.
3
catena-Poly[[[tetra-aqua-nickel(II)]-μ-4,4'-bipyridyl-κN:N'] 3,3'-(p-phenyl-ene)diacrylate].链状聚[[[四水合镍（II）]-μ-4,4'-联吡啶-κN:N'] 3,3'-（对亚苯基）二丙烯酸酯]
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1397. doi: 10.1107/S1600536811036993. Epub 2011 Sep 17.
4
catena-Poly[potassium-di-μ-aqua-μ-4-(5-tetra-zolio)pyridine].链状聚[二水合钾-μ-4-(5-四唑基)吡啶]
Acta Crystallogr Sect E Struct Rep Online. 2009 May 23;65(Pt 6):m671. doi: 10.1107/S1600536809018649.
5
Crystal structure of catena-poly[[di-aqua-cadmium(II)]-μ-3,3'-(1,3-phenyl-ene)diacrylato].链式聚[[二水合镉（II）]-μ-3,3'-（1,3-亚苯基）二丙烯酸酯]的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Mar 21;71(Pt 4):m91-2. doi: 10.1107/S2056989015005411. eCollection 2015 Apr 1.
6
catena-Poly[[[tetra-aqua-cadmium(II)]-μ-4,4'-bipyridine] fumarate tetra-hydrate].链状聚[[[四水合镉（II）]-μ-4,4'-联吡啶]富马酸四水合物]
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m192-3. doi: 10.1107/S1600536807063507.
7
Poly[[bis-[3-(1H-tetra-zol-1-yl)propanoic acid-κN(4)]cadmium]-di-μ-thio-cyanato-κ(2)N:S;κ(2)S:N].聚[[双-[3-(1H-四唑-1-基)丙酸-κN(4)]镉]-二-μ-硫氰酸根合-κ(2)N:S;κ(2)S:N]
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m593-4. doi: 10.1107/S1600536812014730. Epub 2012 Apr 13.
8
catena-Poly[[tetra-aqua-zinc(II)]-μ-2,2'-dihydr-oxy-5,5'-diazenediyldibenzoato].链状聚[[四水合锌（II）]-μ-2,2'-二羟基-5,5'-二氮杂二苯甲酸酯]
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 4;64(Pt 2):m276-7. doi: 10.1107/S1600536807064860.
9
Bis(5-amino-1H-tetra-zole-κN (4))di-aqua-(oxalato-κ(2) O (1),O (2))cadmium.双（5-氨基-1H-四唑-κN(4)）二水合（草酸根-κ(2)O(1),O(2)）镉
Acta Crystallogr Sect E Struct Rep Online. 2013 Nov 9;69(Pt 12):m645-6. doi: 10.1107/S1600536813030158.
10
catena-Poly[[tetra-aqua-copper(II)]-μ-pyrazine-2-carboxamide-κ(3)N(4):N(1),O-[bis-(sulfato-κO)copper(II)]-μ-pyrazine-2-carboxamide-κ(3)N(1),O:N(4)].链状聚[[四水合铜（II）]-μ-吡嗪-2-甲酰胺-κ(3)N(4):N(1),O-[双-(硫酸根-κO)铜（II）]-μ-吡嗪-2-甲酰胺-κ(3)N(1),O:N(4)]
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1082-3. doi: 10.1107/S1600536812031844. Epub 2012 Jul 18.

本文引用的文献

1
A thermally and hydrolytically stable microporous framework exhibiting single-chain magnetism: structure and properties of [Co2(H0.67bdt)3] x 20 H2O.
Angew Chem Int Ed Engl. 2009;48(12):2140-3. doi: 10.1002/anie.200804805.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Microporous metal-organic frameworks incorporating 1,4-benzeneditetrazolate: syntheses, structures, and hydrogen storage properties.包含1,4-苯二四唑酸酯的微孔金属有机骨架：合成、结构及储氢性能
J Am Chem Soc. 2006 Jul 12;128(27):8904-13. doi: 10.1021/ja061716i.
4
Reticular chemistry: occurrence and taxonomy of nets and grammar for the design of frameworks.网状化学：网络的出现与分类以及框架设计的语法规则
Acc Chem Res. 2005 Mar;38(3):176-82. doi: 10.1021/ar020022l.
5
Synthesis and characterization of a tetrazolate-bridged coordination framework encapsulating D2h-symmetric cyclic (H2O)4 cluster arrays.一种封装D2h对称环状(H2O)4簇阵列的四唑盐桥连配位框架的合成与表征
Inorg Chem. 2004 Oct 4;43(20):6133-5. doi: 10.1021/ic0492946.
6
Functional porous coordination polymers.功能性多孔配位聚合物
Angew Chem Int Ed Engl. 2004 Apr 26;43(18):2334-75. doi: 10.1002/anie.200300610.
7
Reticular synthesis and the design of new materials.网状合成与新材料设计
Nature. 2003 Jun 12;423(6941):705-14. doi: 10.1038/nature01650.