• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

链状聚[[[四水合镉（II）]-μ-4,4'-联吡啶]富马酸四水合物]

catena-Poly[[[tetra-aqua-cadmium(II)]-μ-4,4'-bipyridine] fumarate tetra-hydrate].

作者信息

Pan Ya-Ru

机构信息

Department of Chemistry, Tong Hua Teachers' College, Tong Hua 134002, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m192-3. doi: 10.1107/S1600536807063507.

DOI:10.1107/S1600536807063507
PMID:21200540
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915124/
Abstract

In the crystal structure of the title compound, Cd(C(10)H(8)N(2))(H(2)O)(4)·4H(2)O, the Cd(II) atom, on an inversion centre, is six-coordinated by four O atoms from four water mol-ecules and two N atoms from 4,4'-bpy mol-ecules in a distorted octa-hedral coordination geometry. Weak C-H⋯O inter-actions between uncoordinated carboxyl-ate O atoms of fumaric acid and water mol-ecules contribute to the crystal packing stability.

摘要

在标题化合物Cd(C₁₀H₈N₂)(H₂O)₄·4H₂O的晶体结构中，位于对称中心的Cd(II)原子由四个水分子中的四个O原子和4,4'-联吡啶分子中的两个N原子以扭曲的八面体配位几何构型进行六配位。富马酸未配位的羧酸根O原子与水分子之间的弱C-H⋯O相互作用有助于晶体堆积的稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f36b/2915124/1573ae890831/e-64-0m192-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f36b/2915124/a83cf66731a9/e-64-0m192-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f36b/2915124/1573ae890831/e-64-0m192-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f36b/2915124/a83cf66731a9/e-64-0m192-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f36b/2915124/1573ae890831/e-64-0m192-fig2.jpg

相似文献

1
catena-Poly[[[tetra-aqua-cadmium(II)]-μ-4,4'-bipyridine] fumarate tetra-hydrate].链状聚[[[四水合镉（II）]-μ-4,4'-联吡啶]富马酸四水合物]
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m192-3. doi: 10.1107/S1600536807063507.
2
catena-Poly[[[diaqua-iron(II)]-μ-pyridine-2,5-dicarboxyl-ato-[tetra-aqua-iron(II)]-μ-pyridine-2,5-dicarboxyl-ato] tetra-hydrate].链状聚[[[二水合铁（II）]-μ-吡啶-2,5-二羧酸根-[四水合铁（II）]-μ-吡啶-2,5-二羧酸根]四水合物]
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 25;64(Pt 2):m413. doi: 10.1107/S1600536808002043.
3
Poly[[tetra-aqua-tetra-kis-[μ(3)-5-(pyridine-4-carboxamido)-isophthalato]cobalt(II)dierbium(III)] tetra-hydrate].聚[[四水合四-双-[μ(3)-5-(吡啶-4-甲酰胺基)-间苯二甲酸根合]钴(II)二铒(III)]]四水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1478-9. doi: 10.1107/S1600536811039948. Epub 2011 Oct 5.
4
catena-Poly[[[aqua-(5-nitro-benzene-1,2,3-tricarboxyl-ato-κO)nickel(II)]-di-μ-aqua-[diaqua-sodium]-di-μ-aqua] tetra-hydrate].链状聚[[[水合-(5-硝基苯-1,2,3-三羧酸根-κO)镍(II)]-二-μ-水合-[二水合钠]-二-μ-水合]四水合物]
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 27;66(Pt 3):m342. doi: 10.1107/S1600536810006872.
5
catena-Poly[[tetra-aqua-(μ-4,4'-bipyridine-κN:N')zinc(II)] fumarate tetra-hydrate].链状聚[[四水合-(μ-4,4'-联吡啶-κN:N')锌(II)]富马酸四水合物]
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 16;64(Pt 5):m662-3. doi: 10.1107/S1600536808009227.
6
catena-Poly[[octa-aqua-bis-(μ(4)-benzene-1,3,5-tricarboxyl-ato)trizinc] tetra-hydrate].链状聚[[八水双（μ(4)-苯-1,3,5-三羧酸根）三锌]四水合物]
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m630-1. doi: 10.1107/S160053681101436X. Epub 2011 Apr 22.
7
Octa-aqua-bis(μ(2)-1H-pyrazole-3,5-di-carboxyl-ato)tricopper(II) tetra-hydrate.八水合双（μ(2)-1H-吡唑-3,5-二羧酸根）三铜（II）四水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 30;66(Pt 2):m216. doi: 10.1107/S1600536810001595.
8
Poly[octa-μ-aqua-tetra-aqua-bis(μ-5-sul-fon-atobenzene-1,3-dicarboxyl-ato)cobalt(II)tetra-sodium].聚[八-μ-水-四水-双(μ-5-磺酸基苯-1,3-二羧基合)钴(II)四钠]
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 11;65(Pt 4):m387-8. doi: 10.1107/S1600536809008174.
9
Poly[[tetra-aqua-bis-(μ(3)-5-carboxybenzene-1,2,4-tri-carboxyl-ato)tricadmium] tetra-hydrate].聚[[四水合双(μ(3)-5-羧基苯-1,2,4-三羧酸根)三镉]四水合物]
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m801-2. doi: 10.1107/S1600536812022726. Epub 2012 May 26.
10
catena-Poly[[[aqua-(5-nitro-benzene-1,2,3-tricarboxyl-ato-κO)copper(II)]-di-μ-aqua-[diaqua-sodium]-di-μ-aqua] tetra-hydrate].链状聚[[[水合-(5-硝基苯-1,2,3-三羧酸根-κO)铜(II)]-二-μ-水合-[二水合钠]-二-μ-水合]四水合物]
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):m132-3. doi: 10.1107/S1600536810000401.

本文引用的文献

1
Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of [Mn(ph)(Phen)(2)(H(2)O)]. 4H(2)O, [Mn(Phen)(2)(H(2)O)(2)](2)(Isoph)(2)(Phen). 12H(2)O and {[Mn(Isoph)(bipy)](4). 2.75biby}(n)(phH(2) = Phthalic Acid; isoph = Isophthalic Acid; phen = 1,10-Phenanthroline; bipy = 2,2-Bipyridine).邻苯二甲酸和间苯二甲酸锰（II）配合物的合成及生物活性：[Mn(ph)(Phen)(2)(H(2)O)]. 4H(2)O、[Mn(Phen)(2)(H(2)O)(2)](2)(Isoph)(2)(Phen). 12H(2)O和{[Mn(Isoph)(bipy)](4). 2.75biby}(n)的X射线晶体结构（phH(2)=邻苯二甲酸；isoph=间苯二甲酸；phen=1,10-菲咯啉；bipy=2,2-联吡啶）
Met Based Drugs. 2000;7(5):275-88. doi: 10.1155/MBD.2000.275.