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空气喷射对鼓泡塔反应器中空纤维膜的流体动力学影响。

Hydrodynamic effects of air sparging on hollow fiber membranes in a bubble column reactor.

机构信息

Singapore Membrane Technology Centre, Singapore, Singapore.

出版信息

Water Res. 2013 Jul 1;47(11):3762-72. doi: 10.1016/j.watres.2013.04.042. Epub 2013 May 2.

Abstract

Air sparging is now a standard approach to reduce concentration polarization and fouling of membrane modules in membrane bioreactors (MBRs). The hydrodynamic shear stresses, bubble-induced turbulence and cross flows scour the membrane surfaces and help reduce the deposit of foulants onto the membrane surface. However, the detailed quantitative knowledge on the effect of air sparging remains lacking in the literature due to the complex hydrodynamics generated by the gas-liquid flows. To date, there is no valid model that describes the relationship between the membrane fouling performance and the flow hydrodynamics. The present study aims to examine the impact of hydrodynamics induced by air sparging on the membrane fouling mitigation in a quantitative manner. A modelled hollow fiber module was placed in a cylindrical bubble column reactor at different axial heights with the trans-membrane pressure (TMP) monitored under constant flux conditions. The configuration of bubble column without the membrane module immersed was identical to that studied by Gan et al. (2011) using Phase Doppler Anemometry (PDA), to ensure a good quantitative understanding of turbulent flow conditions along the column height. The experimental results showed that the meandering flow regime which exhibits high flow instability at the 0.3 m is more beneficial to fouling alleviation compared with the steady flow circulation regime at the 0.6 m. The filtration tests also confirmed the existence of an optimal superficial air velocity beyond which a further increase is of no significant benefit on the membrane fouling reduction. In addition, the alternate aeration provided by two air stones mounted at the opposite end of the diameter of the bubble column was also studied to investigate the associated flow dynamics and its influence on the membrane filtration performance. It was found that with a proper switching interval and membrane module orientation, the membrane fouling can be effectively controlled with even smaller superficial air velocity than the optimal value provided by a single air stone. Finally, the testing results with both inorganic and organic feeds showed that the solid particle composition and particle size distribution all contribute to the cake formation in a membrane filtration system.

摘要

气提现在是一种标准的方法,用于减少膜生物反应器(MBR)中膜模块的浓差极化和污染。水动力剪切应力、气泡诱导的湍流和交叉流冲刷膜表面,有助于减少污染物在膜表面的沉积。然而,由于气液流动产生的复杂水动力,文献中仍然缺乏关于气提效果的定量知识。迄今为止,还没有有效的模型来描述膜污染性能与流动水动力之间的关系。本研究旨在定量研究气提产生的水动力对膜污染缓解的影响。在恒通量条件下,将模型化的中空纤维模块放置在圆柱形鼓泡塔反应器的不同轴向高度处,并监测跨膜压力(TMP)。没有浸入膜模块的鼓泡塔的配置与 Gan 等人(2011 年)使用相位多普勒风速仪(PDA)研究的配置相同,以确保对柱高沿程湍流条件有很好的定量理解。实验结果表明,与 0.6m 处的稳定流循环相比,在 0.3m 处表现出高流动不稳定性的蜿蜒流更有利于污染缓解。过滤测试还证实了存在一个最佳的表面空气速度,超过该速度后,进一步增加对膜污染减少没有显著益处。此外,还研究了安装在鼓泡塔直径相对端的两个空气石提供的交替曝气,以研究相关的流动动力学及其对膜过滤性能的影响。结果发现,通过适当的切换间隔和膜模块取向,可以有效地控制膜污染,即使使用比单个空气石提供的最佳值更小的表面空气速度。最后,用无机和有机进料进行的测试结果表明,固体颗粒组成和粒径分布都对膜过滤系统中的滤饼形成有贡献。

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