Department of Chemical Engineering, Tsinghua University, Beijing 100084, PR China.
Chem Commun (Camb). 2013 Jul 11;49(54):6090-2. doi: 10.1039/c3cc42493f.
A general approach for preparing enzyme-polymer nanoconjugates that respond to temperature in organic media is presented. These nanoconjugates readily dissolve in organic solvents for homogenous catalysis at 40 °C and showed greatly enhanced apparent catalytic activities. The recovery of the soluble enzyme-polymer nanoconjugates is accomplished by temperature-induced precipitation.
本文提出了一种在有机介质中制备对温度响应的酶-聚合物纳米复合物的通用方法。这些纳米复合物在 40°C 下可溶于有机溶剂中进行均相催化，并显示出明显增强的表观催化活性。通过温度诱导沉淀来实现可溶的酶-聚合物纳米复合物的回收。
